Chlorine nitrate is an inorganic compound with the formula Cl N O 3 . A mobile pale yellow liquid that explodes on contact with many organic substances , metals and their chlorides .
| Chlorine nitrate | |
|---|---|
 | |
 | |
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| Are common | |
| Systematic name | chlorine nitrate |
| Traditional names | nitrile hypochlorite |
| Chem. formula | ClNO 3 |
| Rat formula | Clono 2 |
| Physical properties | |
| condition | yellowish liquid |
| Molar mass | 97.46 g / mol |
| Density | 1.65 g / cm³ |
| Thermal properties | |
| T. melt. | -107 ° C |
| T. bale. | 22.3 ° C |
| Chemical properties | |
| Solubility in carbon tetrachloride | soluble |
| Solubility in trichlorofluoromethane | soluble [1] |
| Classification | |
| Reg. CAS number | 14545-72-3 |
| PubChem | |
| Smiles | |
| Inchi | |
| ChemSpider | |
| Security | |
| NFPA 704 |  0 3 2 Ox
 |
Getting
The interaction of chlorine oxide (I) and nitric anhydride :
At a lower temperature, the substance can be obtained from chlorine (I) fluoride and anhydrous nitric acid :
Chlorine nitrate is also formed in the stratosphere during the reaction of the ClO radical with nitrogen dioxide [2] :
Application
It can be used as a source of nitrate ions, which, unlike N 2 O 4 and N 2 O 5 , does not complicate the reaction with NO + and NO 2 + cations [3] :
Notes
- ↑ Martin Schmeisser. Chlorine (I) nitrate // Inorganic Syntheses. - McGraw-Hill Book Company, Inc, 1967. - S. 127-130.
- ↑ James J. Margitan: Chlorine nitrate photochemistry. Photolysis products and kinetics of the reaction atomic chlorine + chlorine nitrate (ClONO2) .fwdarw. molecular chlorine + nitrate. In: The Journal of Physical Chemistry. 87, 1983, S. 674–679, DOI : 10.1021 / j100227a029
- ↑ Chlorine nitrate is a yellow liquid with a melting point of 107 °, ... - Chemistry Handbook 21