Injection is the filling of something (form, capacity, cavity) with material in a liquid state of aggregation .
According to GOST 3.1109-82: manufacture of a workpiece or product from liquid material by filling it with a cavity of a given shape and size with subsequent hardening.
In the most common sense, a typical process is the operation of obtaining products , which consists in filling a special container (form) that forms the surface or part of the surface of the manufactured product with liquid material (metals and non-metals) with a further thermo-temporary transition of the liquid material to a solid state of aggregation and obtaining as a result, a solid billet close in configuration, size and properties to the product.
Casting is also called foundry products , art products and handicrafts obtained through casting. The essence of metal casting processes and the task of foundry. Casting (or foundry) is the production method in which shaped blanks of parts are made by pouring molten metal into a pre-prepared casting mold, the cavity of which has the configuration of the workpiece blank. After solidification and cooling of the metal in the mold, a casting-blank of the part is obtained. The main objective of foundry is the manufacture of casting alloys of castings having a diverse configuration with the maximum approximation of their shape and size to the shape and dimensions of the part (when casting it is impossible to obtain a casting whose shape and dimensions correspond to the shape and dimensions of the part).
Casting classification
Casting is classified by:
- Cast material:
- metal - black (from alloys based on iron - steel and cast iron) and non-ferrous (from non-ferrous and precious metals - copper, aluminum, magnesium, tin, bismuth, lead, silver, gold) and alloys based on them.
- non-metallic - from plastics, polymers, minerals, concrete, gypsum, organic substances, ceramics, glass, salt, slag and other materials.
- Purpose of castings: industrial - technical, domestic, medical, decorative, artistic, etc.
- Precision of dimensions, degree of surface roughness of castings, presence and size of allowance for machining: rough, precise, precision.
- Special requirements for castings.
- Technologies (types, methods, methods) for producing castings: in the earth , in chill molds , in investment casting , under pressure , electroslag , in gasified models , in molds from cold-hardening mixtures, squeezing, in frozen models, centrifugal, continuous, vacuum, etc.
Variants of one technology are possible (for example, investment casting from paraffin-stearin mixtures and investment casting from fusible alloys) and a combination of different technologies (for example electroslag chill casting).
Sand casting
Sand casting is the cheapest, coarsest (in terms of dimensional accuracy and surface roughness of castings), but the most massive (up to 75-80% by weight of castings obtained in the world) casting. Initially, a casting model is made (previously - a wooden one, nowadays metal or plastic models obtained by rapid prototyping methods are often used), copying the future part. A model mounted on a model plate is covered with sand or sand (usually sand and a binder) that fills the space between it and two open drawers (flasks). Holes and cavities in the part are formed using sand-shaped casting rods placed in the form, copying the shape of the future hole. The mixture poured into the flask is compacted by shaking, pressing, or hardens in a thermal cabinet (drying oven). The resulting cavities are poured with molten metal through special openings - gates. After cooling, the mold is broken and the casting is removed. After that, the sprue system is separated (usually a stump), the flash is removed and the heat treatment is carried out.
To obtain castings using this method, various molding materials can be used, for example, sand-clay mixture or sand mixed with resin, etc. A mold is used to form the mold (a metal box without a bottom and a lid). The flask has two half-forms, that is, it consists of two boxes. The plane of contact of the two half-forms is the surface of the connector. The molding mixture is poured into the mold and rammed. An imprint of the model is made on the surface of the connector (the model corresponds to the shape of the cast). A second half-mold is also performed. Two half-molds are connected along the surface of the connector and metal is poured.
A new area of ββsand casting technology is the use of evacuated dry sand molds without a binder.
Vacuum film casting
The technology of casting in vacuum-film molds (HFF) is a process of shaping due to quartz sand without binder mixtures. The sand form is held due to the force of the vacuum created inside the form. Castings used in the process of the model are made of wood or plastic and have a high operational life, since during the manufacturing of molds the model is covered with a film and does not come into contact with the sand, which eliminates its wear.
Creating a form for filling takes place in 4 stages:
1) the model of the future product is covered with a plastic film and coated with non-stick paint;
2) a flask is installed on the model, sand is poured into the flask, the form is vibro-compacted;
3) the flask is covered from above with a plastic film, and the form is evacuated;
4) the flask is separated from the model.
The mold is poured with metal in the same way as in sand casting. Emissions and odors present during the combustion of mold materials from contact with liquid metal are sucked in by a vacuum system, not released into the atmosphere, which indicates the environmental friendliness of the process.
The method of vacuum-film molding is considered to be the exact type of casting, allowing to produce castings with a small wall thickness. This method is used in the manufacture of steel, cast iron, aluminum and magnesium castings. The advantage of the method is the high quality of molding, the surface of the casting is smooth and clean, not requiring additional machining, which significantly reduces the cost of products.
Chill casting
Metal casting in a chill mold is a better way. A chill mold is made - a collapsible form (most often metal) into which casting is made. After solidification and cooling, the chill mold is opened and the product is removed from it. Then the chill mold can be reused to cast the same part. Unlike other methods of casting into metal molds (injection molding, centrifugal casting, etc.), when casting in a chill mold is filled with liquid alloy and hardens without any external effect on the liquid metal, but only under the action of gravity .
The main operations and processes: cleaning the chill mold from the old cladding, warming it up to 200-300 Β° C, coating the working cavity with a new cladding layer, setting the rods, closing parts of the chill mold, pouring metal, cooling and removing the resulting casting. The process of crystallization of the alloy when casting in a chill mold is accelerated, which contributes to the production of castings with a dense and fine-grained structure, and therefore with good tightness and high physical and mechanical properties. However, castings from cast iron due to the formation of carbides on the surface require subsequent annealing . With repeated use, the chill mold is warped and the dimensions of the castings in the directions perpendicular to the plane of the connector increase.
Castings made of cast iron, steel, aluminum, magnesium and other alloys are obtained in chill molds. Especially effective is the use of chill casting in the manufacture of castings from aluminum and magnesium alloys. These alloys have a relatively low melting point; therefore, one chill mold can be used up to 10,000 times (with the installation of metal rods). Up to 45% of all castings from these alloys are obtained in chill molds. When casting in a chill mold, the range of cooling rates of alloys and the formation of various structures expands. Steel has a relatively high melting point, the resistance of chill molds to steel castings decreases sharply, most surfaces form rods, so the chill casting method for steel is less used than for non-ferrous alloys. This method is widely used in serial and large-scale production.
Injection molding
LPD is one of the leading places in the foundry industry. The production of castings from aluminum alloys in various countries makes up 30-50% of the total output (by weight) of LPD products. The next group in terms of quantity and variety of castings is represented by castings from zinc alloys. Magnesium alloys are less commonly used for injection molding, which is explained by their tendency to form hot cracks and more difficult technological conditions for manufacturing castings. The production of copper alloy castings is limited by the low mold resistance.
The nomenclature of castings produced by the domestic industry is very diverse. In this way, cast billets of the most various configurations are manufactured, weighing from several grams to several tens of kilograms. The following positive aspects of the LPD process are highlighted:
- High productivity and automation of production, along with low labor input for manufacturing one casting, makes the LPD process the most optimal in the conditions of mass and large-scale production.
- Minimum or non-machining allowances, minimum roughness of non-machined surfaces and dimensional accuracy, allowing tolerances of up to Β± 0.075 mm per side.
- The clarity of the resulting relief, which allows castings with a minimum wall thickness of up to 0.6 mm, as well as cast threaded profiles.
- Surface cleanliness on non-machined surfaces, allows casting to give a marketable aesthetic appearance.
Also distinguish the following negative effects of the characteristics of the LPD, leading to a loss of tightness of the castings and the impossibility of their further heat treatment:
- Air porosity, the cause of which is air and gases from a burnt lubricant, captured by the metal stream when filling the mold. What is caused by suboptimal filling conditions, as well as low gas permeability of the form.
- Shrinkage defects, manifested due to the high thermal conductivity of the molds along with difficult nutritional conditions during the hardening process.
- Non-metallic and gas inclusions that appear due to inadequate cleaning of the alloy in the transfer furnace, and also released from the solid solution.
Given the goal of obtaining a casting of a given configuration, it is necessary to clearly determine its purpose: whether high requirements for strength, tightness will be imposed on it, or will its use be limited to the decorative area. The quality of products, as well as the costs of their production, depend on the correct combination of technological modes of LPD. Compliance with the manufacturability conditions of cast parts implies their structural design, which, without reducing the basic requirements for the design, helps to obtain the specified physical and mechanical properties, dimensional accuracy and surface roughness with minimal labor input and limited use of scarce materials. It is always necessary to take into account that the quality of castings obtained by LPD depends on a large number of variable technological factors, the connection between which is extremely difficult to establish because of the speed of filling out the form.
The main parameters affecting the process of filling and forming the casting are as follows:
- pressure on the metal during filling and pre-pressing;
- pressing speed;
- gate-ventilation system design;
- temperature of the cast alloy and mold;
- lubrication and evacuation modes.
By combining and varying these basic parameters, they achieve a reduction in the negative effects of the features of the LPD process. Historically, the following traditional design and technological solutions to reduce marriage have been distinguished:
- temperature control of the cast alloy and mold;
- increased pressure on the metal during filling and pre-pressing;
- refining and refining of the alloy;
- evacuation;
- design of the gate-ventilation system;
Also, there are a number of unconventional solutions aimed at eliminating the negative impact of the features of LPD:
- filling the mold and chamber with active gases;
- the use of a double stroke locking mechanism;
- use of a double piston of a special design;
- installation of a replaceable diaphragm;
- a groove for venting air in the pressing chamber;
Lost wax casting
Another casting method - by investment casting - has been known since ancient times. It is used for the manufacture of parts of high accuracy and complex configuration that are not feasible by other casting methods (for example, turbine blades , etc.)
From the fusible material: paraffin , stearin , etc. (in the simplest case, from wax ), by pressing it into the mold, an exact product model and the gating system are made.
The model is then dipped in a liquid suspension of dusty refractory filler in a binder. A suspension is applied to the model block (model and LPS) and sprinkled, so 6 to 10 layers are applied, with each layer drying. With each subsequent layer, the grain fraction of the dusting is changed to form a dense surface of the shell shape. The model composition is smelted from the formed shell. After drying and heating, the block is calcined at a temperature of about 1000 Β° C to remove gas-forming substances from the shell form.
Then the shells come to fill. Before pouring, the blocks are heated in furnaces to 1000 Β° C. The heated block is installed in the furnace, and the heated metal is poured into the shell. The filled block is cooled in a thermostat or in air. When the block is completely cooled, it is sent to a knockout. Hammer blows on the sprue bowl beats ceramic, then the LPS section. Thus we get a casting.
The advantages of this method: the ability to manufacture parts from alloys that are not amenable to mechanical processing; obtaining castings with an accuracy of sizes up to 11 - 13 quality and surface roughness Ra 2.5-1.25 microns, which in some cases eliminates cutting processing; the possibility of obtaining machine components that, with conventional casting methods, would have to be assembled from separate parts. Lost wax casting is used in a single (pilot), serial and mass production.
Due to the high consumption of metal and the high cost of the process, investment casting is used only for critical parts.
Gasification casting
Foam-casting using gasified models (LGM) is the most profitable for the quality of shaped castings, cost-effectiveness, environmental friendliness and high production culture. World practice indicates a steady increase in the production of castings by this method, which in 2007 exceeded 1.5 million tons / year, it is especially popular in the USA and China (more than 1.5 thousand such sections work in China), where more and more are being poured castings without restrictions in shape and size. In the sand form, the foam model is replaced by molten metal when casting, so a high-precision casting is obtained. Most often, a dry sand mold is evacuated at a level of 50 kPa, but molding is also used in bulk and easily compacted sand mixtures with a binder. The field of application is castings weighing 0.1β2000 kg and more, the tendency to expand the use in serial and mass production of castings with overall dimensions of 40β1000 mm, in particular, in engine building for casting blocks and cylinder heads, etc.
4 types of model-forming (non-metallic) materials are consumed per 1 ton of suitable casting:
- silica sand - 50 kg
- non-stick coating - 25 kg,
- polystyrene foam - 6 kg,
- polyethylene film - 10 sq.m.
ΠΡΡΡΡΡΡΠ²ΠΈΠ΅ ΡΡΠ°Π΄ΠΈΡΠΈΠΎΠ½Π½ΡΡ ΡΠΎΡΠΌ ΠΈ ΡΡΠ΅ΡΠΆΠ½Π΅ΠΉ ΠΈΡΠΊΠ»ΡΡΠ°Π΅Ρ ΠΏΡΠΈΠΌΠ΅Π½Π΅Π½ΠΈΠ΅ ΡΠΎΡΠΌΠΎΠ²ΠΎΡΠ½ΡΡ ΠΈ ΡΡΠ΅ΡΠΆΠ½Π΅Π²ΡΡ ΡΠΌΠ΅ΡΠ΅ΠΉ, ΡΠΎΡΠΌΠΎΠ²ΠΊΠ° ΡΠΎΡΡΠΎΠΈΡ ΠΈΠ· Π·Π°ΡΡΠΏΠΊΠΈ ΠΌΠΎΠ΄Π΅Π»ΠΈ ΠΏΠ΅ΡΠΊΠΎΠΌ Ρ ΠΏΠΎΠ²ΡΠΎΡΠ½ΡΠΌ Π΅Π³ΠΎ ΠΈΡΠΏΠΎΠ»ΡΠ·ΠΎΠ²Π°Π½ΠΈΠ΅ΠΌ Π½Π° 95-97 %.
Π¦Π΅Π½ΡΡΠΎΠ±Π΅ΠΆΠ½ΠΎΠ΅ Π»ΠΈΡΡΡ
Π¦Π΅Π½ΡΡΠΎΠ±Π΅ΠΆΠ½ΡΠΉ ΠΌΠ΅ΡΠΎΠ΄ Π»ΠΈΡΡΡ (ΡΠ΅Π½ΡΡΠΎΠ±Π΅ΠΆΠ½ΠΎΠ΅ Π»ΠΈΡΡΡ) ΠΈΡΠΏΠΎΠ»ΡΠ·ΡΠ΅ΡΡΡ ΠΏΡΠΈ ΠΏΠΎΠ»ΡΡΠ΅Π½ΠΈΠΈ ΠΎΡΠ»ΠΈΠ²ΠΎΠΊ, ΠΈΠΌΠ΅ΡΡΠΈΡ ΡΠΎΡΠΌΡ ΡΠ΅Π» Π²ΡΠ°ΡΠ΅Π½ΠΈΡ. ΠΠΎΠ΄ΠΎΠ±Π½ΡΠ΅ ΠΎΡΠ»ΠΈΠ²ΠΊΠΈ ΠΎΡΠ»ΠΈΠ²Π°ΡΡΡΡ ΠΈΠ· ΡΡΠ³ΡΠ½Π°, ΡΡΠ°Π»ΠΈ, Π±ΡΠΎΠ½Π·Ρ ΠΈ Π°Π»ΡΠΌΠΈΠ½ΠΈΡ. ΠΡΠΈ ΡΡΠΎΠΌ ΡΠ°ΡΠΏΠ»Π°Π² Π·Π°Π»ΠΈΠ²Π°ΡΡ Π² ΠΌΠ΅ΡΠ°Π»Π»ΠΈΡΠ΅ΡΠΊΡΡ ΡΠΎΡΠΌΡ, Π²ΡΠ°ΡΠ°ΡΡΡΡΡΡ ΡΠΎ ΡΠΊΠΎΡΠΎΡΡΡΡ 3000 ΠΎΠ±/ΠΌΠΈΠ½.
ΠΠΎΠ΄ Π΄Π΅ΠΉΡΡΠ²ΠΈΠ΅ΠΌ ΡΠ΅Π½ΡΡΠΎΠ±Π΅ΠΆΠ½ΠΎΠΉ ΡΠΈΠ»Ρ ΡΠ°ΡΠΏΠ»Π°Π² ΡΠ°ΡΠΏΡΠ΅Π΄Π΅Π»ΡΠ΅ΡΡΡ ΠΏΠΎ Π²Π½ΡΡΡΠ΅Π½Π½Π΅ΠΉ ΠΏΠΎΠ²Π΅ΡΡ Π½ΠΎΡΡΠΈ ΡΠΎΡΠΌΡ ΠΈ, ΠΊΡΠΈΡΡΠ°Π»Π»ΠΈΠ·ΡΡΡΡ, ΠΎΠ±ΡΠ°Π·ΡΠ΅Ρ ΠΎΡΠ»ΠΈΠ²ΠΊΡ. Π¦Π΅Π½ΡΡΠΎΠ±Π΅ΠΆΠ½ΡΠΌ ΡΠΏΠΎΡΠΎΠ±ΠΎΠΌ ΠΌΠΎΠΆΠ½ΠΎ ΠΏΠΎΠ»ΡΡΠΈΡΡ Π΄Π²ΡΡ ΡΠ»ΠΎΠΉΠ½ΡΠ΅ Π·Π°Π³ΠΎΡΠΎΠ²ΠΊΠΈ, ΡΡΠΎ Π΄ΠΎΡΡΠΈΠ³Π°Π΅ΡΡΡ ΠΏΠΎΠΎΡΠ΅ΡΡΠ΄Π½ΠΎΠΉ Π·Π°Π»ΠΈΠ²ΠΊΠΎΠΉ Π² ΡΠΎΡΠΌΡ ΡΠ°Π·Π»ΠΈΡΠ½ΡΡ ΡΠΏΠ»Π°Π²ΠΎΠ². ΠΡΠΈΡΡΠ°Π»Π»ΠΈΠ·Π°ΡΠΈΡ ΡΠ°ΡΠΏΠ»Π°Π²Π° Π² ΠΌΠ΅ΡΠ°Π»Π»ΠΈΡΠ΅ΡΠΊΠΎΠΉ ΡΠΎΡΠΌΠ΅ ΠΏΠΎΠ΄ Π΄Π΅ΠΉΡΡΠ²ΠΈΠ΅ΠΌ ΡΠ΅Π½ΡΡΠΎΠ±Π΅ΠΆΠ½ΠΎΠΉ ΡΠΈΠ»Ρ ΠΎΠ±Π΅ΡΠΏΠ΅ΡΠΈΠ²Π°Π΅Ρ ΠΏΠΎΠ»ΡΡΠ΅Π½ΠΈΠ΅ ΠΏΠ»ΠΎΡΠ½ΡΡ ΠΎΡΠ»ΠΈΠ²ΠΎΠΊ.
ΠΡΠΈ ΡΡΠΎΠΌ, ΠΊΠ°ΠΊ ΠΏΡΠ°Π²ΠΈΠ»ΠΎ, Π² ΠΎΡΠ»ΠΈΠ²ΠΊΠ°Ρ Π½Π΅ Π±ΡΠ²Π°Π΅Ρ Π³Π°Π·ΠΎΠ²ΡΡ ΡΠ°ΠΊΠΎΠ²ΠΈΠ½ ΠΈ ΡΠ»Π°ΠΊΠΎΠ²ΡΡ Π²ΠΊΠ»ΡΡΠ΅Π½ΠΈΠΉ. ΠΡΠΎΠ±ΡΠΌΠΈ ΠΏΡΠ΅ΠΈΠΌΡΡΠ΅ΡΡΠ²Π°ΠΌΠΈ ΡΠ΅Π½ΡΡΠΎΠ±Π΅ΠΆΠ½ΠΎΠ³ΠΎ Π»ΠΈΡΡΡ ΡΠ²Π»ΡΠ΅ΡΡΡ ΠΏΠΎΠ»ΡΡΠ΅Π½ΠΈΠ΅ Π²Π½ΡΡΡΠ΅Π½Π½ΠΈΡ ΠΏΠΎΠ»ΠΎΡΡΠ΅ΠΉ Π±Π΅Π· ΠΏΡΠΈΠΌΠ΅Π½Π΅Π½ΠΈΡ ΡΡΠ΅ΡΠΆΠ½Π΅ΠΉ ΠΈ Π±ΠΎΠ»ΡΡΠ°Ρ ΡΠΊΠΎΠ½ΠΎΠΌΠΈΡ ΡΠΏΠ»Π°Π²Π° Π² Π²ΠΈΠ΄Ρ ΠΎΡΡΡΡΡΡΠ²ΠΈΡ Π»ΠΈΡΠ½ΠΈΠΊΠΎΠ²ΠΎΠΉ ΡΠΈΡΡΠ΅ΠΌΡ. ΠΡΡ ΠΎΠ΄ Π³ΠΎΠ΄Π½ΡΡ ΠΎΡΠ»ΠΈΠ²ΠΎΠΊ ΠΏΠΎΠ²ΡΡΠ°Π΅ΡΡΡ Π΄ΠΎ 95 %.
Π¨ΠΈΡΠΎΠΊΠΈΠΌ ΡΠΏΡΠΎΡΠΎΠΌ ΠΏΠΎΠ»ΡΠ·ΡΡΡΡΡ ΠΎΡΠ»ΠΈΠ²ΠΊΠΈ Π²ΡΡΠ»ΠΎΠΊ, Π³ΠΈΠ»ΡΠ· ΠΈ Π΄ΡΡΠ³ΠΈΡ Π·Π°Π³ΠΎΡΠΎΠ²ΠΎΠΊ, ΠΈΠΌΠ΅ΡΡΠΈΡ ΡΠΎΡΠΌΡ ΡΠ΅Π»Π° Π²ΡΠ°ΡΠ΅Π½ΠΈΡ, ΠΏΡΠΎΠΈΠ·Π²Π΅Π΄ΡΠ½Π½ΡΠ΅ Ρ ΠΏΠΎΠΌΠΎΡΡΡ ΠΌΠ΅ΡΠΎΠ΄Π° ΡΠ΅Π½ΡΡΠΎΠ±Π΅ΠΆΠ½ΠΎΠ³ΠΎ Π»ΠΈΡΡΡ.
Π¦Π΅Π½ΡΡΠΎΠ±Π΅ΠΆΠ½ΠΎΠ΅ Π»ΠΈΡΡΡ β ΡΡΠΎ ΡΠΏΠΎΡΠΎΠ± ΠΏΠΎΠ»ΡΡΠ΅Π½ΠΈΡ ΠΎΡΠ»ΠΈΠ²ΠΎΠΊ Π² ΠΌΠ΅ΡΠ°Π»Π»ΠΈΡΠ΅ΡΠΊΠΈΡ ΡΠΎΡΠΌΠ°Ρ . ΠΡΠΈ ΡΠ΅Π½ΡΡΠΎΠ±Π΅ΠΆΠ½ΠΎΠΌ Π»ΠΈΡΡΠ΅ ΡΠ°ΡΠΏΠ»Π°Π²Π»Π΅Π½Π½ΡΠΉ ΠΌΠ΅ΡΠ°Π»Π», ΠΏΠΎΠ΄Π²Π΅ΡΠ³Π°ΡΡΡ Π΄Π΅ΠΉΡΡΠ²ΠΈΡ ΡΠ΅Π½ΡΡΠΎΠ±Π΅ΠΆΠ½ΡΡ ΡΠΈΠ», ΠΎΡΠ±ΡΠ°ΡΡΠ²Π°Π΅ΡΡΡ ΠΊ ΡΡΠ΅Π½ΠΊΠ°ΠΌ ΡΠΎΡΠΌΡ ΠΈ Π·Π°ΡΠ²Π΅ΡΠ΄Π΅Π²Π°Π΅Ρ. Π’Π°ΠΊΠΈΠΌ ΠΎΠ±ΡΠ°Π·ΠΎΠΌ ΠΏΠΎΠ»ΡΡΠ°Π΅ΡΡΡ ΠΎΡΠ»ΠΈΠ²ΠΊΠ°. ΠΡΠΎΡ ΡΠΏΠΎΡΠΎΠ± Π»ΠΈΡΡΡ ΡΠΈΡΠΎΠΊΠΎ ΠΈΡΠΏΠΎΠ»ΡΠ·ΡΠ΅ΡΡΡ Π² ΠΏΡΠΎΠΌΡΡΠ»Π΅Π½Π½ΠΎΡΡΠΈ, ΠΎΡΠΎΠ±Π΅Π½Π½ΠΎ Π΄Π»Ρ ΠΏΠΎΠ»ΡΡΠ΅Π½ΠΈΡ ΠΏΡΡΡΠΎΡΠ΅Π»ΡΡ ΠΎΡΠ»ΠΈΠ²ΠΎΠΊ (ΡΠΎ ΡΠ²ΠΎΠ±ΠΎΠ΄Π½ΠΎΠΉ ΠΏΠΎΠ²Π΅ΡΡ Π½ΠΎΡΡΡΡ).
Π’Π΅Ρ Π½ΠΎΠ»ΠΎΠ³ΠΈΡ ΡΠ΅Π½ΡΡΠΎΠ±Π΅ΠΆΠ½ΠΎΠ³ΠΎ Π»ΠΈΡΡΡ ΠΎΠ±Π΅ΡΠΏΠ΅ΡΠΈΠ²Π°Π΅Ρ ΡΠ΅Π»ΡΠΉ ΡΡΠ΄ ΠΏΡΠ΅ΠΈΠΌΡΡΠ΅ΡΡΠ², Π·Π°ΡΠ°ΡΡΡΡ Π½Π΅Π΄ΠΎΡΡΠΈΠΆΠΈΠΌΡΡ ΠΏΡΠΈ Π΄ΡΡΠ³ΠΈΡ ΡΠΏΠΎΡΠΎΠ±Π°Ρ , ΠΊ ΠΏΡΠΈΠΌΠ΅ΡΡ:
- ΠΡΡΠΎΠΊΠ°Ρ ΠΈΠ·Π½ΠΎΡΠΎΡΡΠΎΠΉΠΊΠΎΡΡΡ.
- ΠΡΡΠΎΠΊΠ°Ρ ΠΏΠ»ΠΎΡΠ½ΠΎΡΡΡ ΠΌΠ΅ΡΠ°Π»Π»Π°.
- ΠΡΡΡΡΡΡΠ²ΠΈΠ΅ ΡΠ°ΠΊΠΎΠ²ΠΈΠ½.
- Π ΠΏΡΠΎΠ΄ΡΠΊΡΠΈΠΈ ΡΠ΅Π½ΡΡΠΎΠ±Π΅ΠΆΠ½ΠΎΠ³ΠΎ Π»ΠΈΡΡΡ ΠΎΡΡΡΡΡΡΠ²ΡΡΡ Π½Π΅ΠΌΠ΅ΡΠ°Π»Π»ΠΈΡΠ΅ΡΠΊΠΈΠ΅ Π²ΠΊΠ»ΡΡΠ΅Π½ΠΈΡ ΠΈ ΡΠ»Π°ΠΊ.
Π¦Π΅Π½ΡΡΠΎΠ±Π΅ΠΆΠ½ΡΠΌ Π»ΠΈΡΡΡΠΌ ΠΏΠΎΠ»ΡΡΠ°ΡΡ Π»ΠΈΡΡΠ΅ Π·Π°Π³ΠΎΡΠΎΠ²ΠΊΠΈ, ΠΈΠΌΠ΅ΡΡΠΈΠ΅ ΡΠΎΡΠΌΡ ΡΠ΅Π» Π²ΡΠ°ΡΠ΅Π½ΠΈΡ:
- Π²ΡΡΠ»ΠΊΠΈ;
- Π²Π΅Π½ΡΡ ΡΠ΅ΡΠ²ΡΡΠ½ΡΡ ΠΊΠΎΠ»ΡΡ;
- Π±Π°ΡΠ°Π±Π°Π½Ρ Π΄Π»Ρ Π±ΡΠΌΠ°Π³ΠΎΠ΄Π΅Π»Π°ΡΠ΅Π»ΡΠ½ΡΡ ΠΌΠ°ΡΠΈΠ½;
- ΡΠΎΡΠΎΡΡ ΡΠ»Π΅ΠΊΡΡΠΎΠ΄Π²ΠΈΠ³Π°ΡΠ΅Π»Π΅ΠΉ.
ΠΠ°ΠΈΠ±ΠΎΠ»ΡΡΠ΅Π΅ ΠΏΡΠΈΠΌΠ΅Π½Π΅Π½ΠΈΠ΅ ΡΠ΅Π½ΡΡΠΎΠ±Π΅ΠΆΠ½ΠΎΠ΅ Π»ΠΈΡΡΡ Π½Π°Ρ ΠΎΠ΄ΠΈΡ ΠΏΡΠΈ ΠΈΠ·Π³ΠΎΡΠΎΠ²Π»Π΅Π½ΠΈΠΈ Π²ΡΡΠ»ΠΎΠΊ ΠΈΠ· ΠΌΠ΅Π΄Π½ΡΡ ΡΠΏΠ»Π°Π²ΠΎΠ², ΠΏΡΠ΅ΠΈΠΌΡΡΠ΅ΡΡΠ²Π΅Π½Π½ΠΎ ΠΎΠ»ΠΎΠ²ΡΠ½Π½ΡΡ Π±ΡΠΎΠ½Π·.
ΠΠΎ ΡΡΠ°Π²Π½Π΅Π½ΠΈΡ Ρ Π»ΠΈΡΡΡΠΌ Π² Π½Π΅ΠΏΠΎΠ΄Π²ΠΈΠΆΠ½ΡΠ΅ ΡΠΎΡΠΌΡ ΡΠ΅Π½ΡΡΠΎΠ±Π΅ΠΆΠ½ΠΎΠ΅ Π»ΠΈΡΡΡ ΠΈΠΌΠ΅Π΅Ρ ΡΡΠ΄ ΠΏΡΠ΅ΠΈΠΌΡΡΠ΅ΡΡΠ²: ΠΏΠΎΠ²ΡΡΠ°ΡΡΡΡ Π·Π°ΠΏΠΎΠ»Π½ΡΠ΅ΠΌΠΎΡΡΡ ΡΠΎΡΠΌ, ΠΏΠ»ΠΎΡΠ½ΠΎΡΡΡ ΠΈ ΠΌΠ΅Ρ Π°Π½ΠΈΡΠ΅ΡΠΊΠΈΠ΅ ΡΠ²ΠΎΠΉΡΡΠ²Π° ΠΎΡΠ»ΠΈΠ²ΠΎΠΊ, Π²ΡΡ ΠΎΠ΄ Π³ΠΎΠ΄Π½ΠΎΠ³ΠΎ. ΠΠ΄Π½Π°ΠΊΠΎ Π΄Π»Ρ Π΅Π³ΠΎ ΠΎΡΠ³Π°Π½ΠΈΠ·Π°ΡΠΈΠΈ Π½Π΅ΠΎΠ±Ρ ΠΎΠ΄ΠΈΠΌΠΎ ΡΠΏΠ΅ΡΠΈΠ°Π»ΡΠ½ΠΎΠ΅ ΠΎΠ±ΠΎΡΡΠ΄ΠΎΠ²Π°Π½ΠΈΠ΅; Π½Π΅Π΄ΠΎΡΡΠ°ΡΠΊΠΈ, ΠΏΡΠΈΡΡΡΠΈΠ΅ ΡΡΠΎΠΌΡ ΡΠΏΠΎΡΠΎΠ±Ρ Π»ΠΈΡΡΡ: Π½Π΅ΡΠΎΡΠ½ΠΎΡΡΡ ΡΠ°Π·ΠΌΠ΅ΡΠΎΠ² ΡΠ²ΠΎΠ±ΠΎΠ΄Π½ΡΡ ΠΏΠΎΠ²Π΅ΡΡ Π½ΠΎΡΡΠ΅ΠΉ ΠΎΡΠ»ΠΈΠ²ΠΎΠΊ, ΠΏΠΎΠ²ΡΡΠ΅Π½Π½Π°Ρ ΡΠΊΠ»ΠΎΠ½Π½ΠΎΡΡΡ ΠΊ Π»ΠΈΠΊΠ²Π°ΡΠΈΠΈ ΠΊΠΎΠΌΠΏΠΎΠ½Π΅Π½ΡΠΎΠ² ΡΠΏΠ»Π°Π²Π°, ΠΏΠΎΠ²ΡΡΠ΅Π½Π½ΡΠ΅ ΡΡΠ΅Π±ΠΎΠ²Π°Π½ΠΈΡ ΠΊ ΠΏΡΠΎΡΠ½ΠΎΡΡΠΈ Π»ΠΈΡΠ΅ΠΉΠ½ΡΡ ΡΠΎΡΠΌ.
ΠΠΈΡΡΡ Π² ΠΎΠ±ΠΎΠ»ΠΎΡΠΊΠΎΠ²ΡΠ΅ ΡΠΎΡΠΌΡ
ΠΠΈΡΡΡ Π² ΠΎΠ±ΠΎΠ»ΠΎΡΠΊΠΎΠ²ΡΠ΅ ΡΠΎΡΠΌΡ β ΡΠΏΠΎΡΠΎΠ± ΠΏΠΎΠ»ΡΡΠ΅Π½ΠΈΡ ΡΠ°ΡΠΎΠ½Π½ΡΡ ΠΎΡΠ»ΠΈΠ²ΠΎΠΊ ΠΈΠ· ΠΌΠ΅ΡΠ°Π»Π»ΠΈΡΠ΅ΡΠΊΠΈΡ ΡΠΏΠ»Π°Π²ΠΎΠ² Π² ΡΠΎΡΠΌΠ°Ρ , ΡΠΎΡΡΠΎΡΡΠΈΡ ΠΈΠ· ΡΠΌΠ΅ΡΠΈ ΠΏΠ΅ΡΡΠ°Π½ΡΡ Π·ΡΡΠ΅Π½ (ΠΎΠ±ΡΡΠ½ΠΎ ΠΊΠ²Π°ΡΡΠ΅Π²ΡΡ ) ΠΈ ΡΠΈΠ½ΡΠ΅ΡΠΈΡΠ΅ΡΠΊΠΎΠ³ΠΎ ΠΏΠΎΡΠΎΡΠΊΠ° (ΠΎΠ±ΡΡΠ½ΠΎ ΡΠ΅Π½ΠΎΠ»ΠΎΡΠΎΡΠΌΠ°Π»ΡΠ΄Π΅Π³ΠΈΠ΄Π½ΠΎΠΉ ΡΠΌΠΎΠ»Ρ ΠΈ ΠΏΡΠ»ΡΠ²Π΅Ρ-Π±Π°ΠΊΠ΅Π»ΠΈΡΠ°). ΠΡΠ΅Π΄ΠΏΠΎΡΡΠΈΡΠ΅Π»ΡΠ½ΠΎ ΠΏΡΠΈΠΌΠ΅Π½Π΅Π½ΠΈΠ΅ ΠΏΠ»Π°ΠΊΠΈΡΠΎΠ²Π°Π½Π½ΡΡ ΠΏΠ΅ΡΡΠ°Π½ΡΡ Π·ΡΡΠ΅Π½ (ΠΏΠΎΠΊΡΡΡΡΡ ΡΠ»ΠΎΠ΅ΠΌ ΡΠΈΠ½ΡΠ΅ΡΠΈΡΠ΅ΡΠΊΠΎΠΉ ΡΠΌΠΎΠ»Ρ).
ΠΠ±ΠΎΠ»ΠΎΡΠΊΠΎΠ²ΡΡ ΡΠΎΡΠΌΡ ΠΏΠΎΠ»ΡΡΠ°ΡΡ ΠΎΠ΄Π½ΠΈΠΌ ΠΈΠ· Π΄Π²ΡΡ ΠΌΠ΅ΡΠΎΠ΄ΠΎΠ². Π‘ΠΌΠ΅ΡΡ Π½Π°ΡΡΠΏΠ°ΡΡ Π½Π° ΠΌΠ΅ΡΠ°Π»Π»ΠΈΡΠ΅ΡΠΊΡΡ ΠΌΠΎΠ΄Π΅Π»Ρ, Π½Π°Π³ΡΠ΅ΡΡΡ Π΄ΠΎ 300 Β°C, Π²ΡΠ΄Π΅ΡΠΆΠΈΠ²Π°ΡΡ Π² ΡΠ΅ΡΠ΅Π½ΠΈΠ΅ Π½Π΅ΡΠΊΠΎΠ»ΡΠΊΠΈΡ Π΄Π΅ΡΡΡΠΊΠΎΠ² ΡΠ΅ΠΊΡΠ½Π΄ Π΄ΠΎ ΠΎΠ±ΡΠ°Π·ΠΎΠ²Π°Π½ΠΈΡ ΡΠΎΠ½ΠΊΠΎΠ³ΠΎ ΡΠΏΡΠΎΡΠ½ΡΠ½Π½ΠΎΠ³ΠΎ ΡΠ»ΠΎΡ, ΠΈΠ·Π±ΡΡΠΎΠΊ ΡΠΌΠ΅ΡΠΈ ΡΠ΄Π°Π»ΡΡΡ. ΠΡΠΈ ΠΈΡΠΏΠΎΠ»ΡΠ·ΠΎΠ²Π°Π½ΠΈΠΈ ΠΏΠ»Π°ΠΊΠΈΡΠΎΠ²Π°Π½Π½ΠΎΠΉ ΡΠΌΠ΅ΡΠΈ Π΅Ρ Π²Π΄ΡΠ²Π°ΡΡ Π² Π·Π°Π·ΠΎΡ ΠΌΠ΅ΠΆΠ΄Ρ Π½Π°Π³ΡΠ΅ΡΠΎΠΉ ΠΌΠΎΠ΄Π΅Π»ΡΡ ΠΈ Π½Π°ΡΡΠΆΠ½ΠΎΠΉ ΠΊΠΎΠ½ΡΡΡΠ½ΠΎΠΉ ΠΏΠ»ΠΈΡΠΎΠΉ. Π ΠΎΠ±ΠΎΠΈΡ ΡΠ»ΡΡΠ°ΡΡ Π½Π΅ΠΎΠ±Ρ ΠΎΠ΄ΠΈΠΌΠΎ Π΄ΠΎΡΠΏΡΠΎΡΠ½Π΅Π½ΠΈΠ΅ ΠΎΠ±ΠΎΠ»ΠΎΡΠΊΠΈ Π² ΠΏΠ΅ΡΠΈ (ΠΏΡΠΈ ΡΠ΅ΠΌΠΏΠ΅ΡΠ°ΡΡΡΠ΅ Π΄ΠΎ 600β700 Β°C) Π½Π° ΠΌΠΎΠ΄Π΅Π»ΠΈ. ΠΠΎΠ»ΡΡΠ΅Π½Π½ΡΠ΅ ΠΎΠ±ΠΎΠ»ΠΎΡΠΊΠΎΠ²ΡΠ΅ ΠΏΠΎΠ»ΡΡΠΎΡΠΌΡ ΡΠΊΡΠ΅ΠΏΠ»ΡΡΡ, ΠΈ Π² Π½ΠΈΡ Π·Π°Π»ΠΈΠ²Π°ΡΡ ΠΆΠΈΠ΄ΠΊΠΈΠΉ ΡΠΏΠ»Π°Π². ΠΠΎ ΠΈΠ·Π±Π΅ΠΆΠ°Π½ΠΈΠ΅ Π΄Π΅ΡΠΎΡΠΌΠ°ΡΠΈΠΈ ΡΠΎΡΠΌ ΠΏΠΎΠ΄ Π΄Π΅ΠΉΡΡΠ²ΠΈΠ΅ΠΌ Π·Π°Π»ΠΈΠ²Π°Π΅ΠΌΠΎΠ³ΠΎ ΡΠΏΠ»Π°Π²Π° ΠΏΠ΅ΡΠ΅Π΄ Π·Π°Π»ΠΈΠ²ΠΊΠΎΠΉ ΠΈΡ ΠΏΠΎΠΌΠ΅ΡΠ°ΡΡ Π² ΠΌΠ΅ΡΠ°Π»Π»ΠΈΡΠ΅ΡΠΊΠΈΠΉ ΠΊΠΎΠΆΡΡ , Π° ΠΏΡΠΎΡΡΡΠ°Π½ΡΡΠ²ΠΎ ΠΌΠ΅ΠΆΠ΄Ρ Π΅Π³ΠΎ ΡΡΠ΅Π½ΠΊΠ°ΠΌΠΈ ΠΈ ΡΠΎΡΠΌΠΎΠΉ Π·Π°ΠΏΠΎΠ»Π½ΡΡΡ ΠΌΠ΅ΡΠ°Π»Π»ΠΈΡΠ΅ΡΠΊΠΎΠΉ Π΄ΡΠΎΠ±ΡΡ, Π½Π°Π»ΠΈΡΠΈΠ΅ ΠΊΠΎΡΠΎΡΠΎΠΉ Π²ΠΎΠ·Π΄Π΅ΠΉΡΡΠ²ΡΠ΅Ρ ΡΠ°ΠΊΠΆΠ΅ Π½Π° ΡΠ΅ΠΌΠΏΠ΅ΡΠ°ΡΡΡΠ½ΡΠΉ ΡΠ΅ΠΆΠΈΠΌ ΠΎΡ Π»Π°ΠΆΠ΄Π°ΡΡΠ΅ΠΉΡΡ ΠΎΡΠ»ΠΈΠ²ΠΊΠΈ.
ΠΡΠΈΠΌ ΡΠΏΠΎΡΠΎΠ±ΠΎΠΌ ΠΈΠ·Π³ΠΎΡΠ°Π²Π»ΠΈΠ²Π°ΡΡ ΡΠ°Π·Π»ΠΈΡΠ½ΡΠ΅ ΠΎΡΠ»ΠΈΠ²ΠΊΠΈ ΠΌΠ°ΡΡΠΎΠΉ Π΄ΠΎ 25 ΠΊΠ³. ΠΡΠ΅ΠΈΠΌΡΡΠ΅ΡΡΠ²Π°ΠΌΠΈ ΡΠΏΠΎΡΠΎΠ±Π° ΡΠ²Π»ΡΡΡΡΡ Π·Π½Π°ΡΠΈΡΠ΅Π»ΡΠ½ΡΠ΅ ΠΏΠΎΠ²ΡΡΠ΅Π½ΠΈΠ΅ ΠΏΡΠΎΠΈΠ·Π²ΠΎΠ΄ΠΈΡΠ΅Π»ΡΠ½ΠΎΡΡΠΈ ΠΏΠΎ ΡΡΠ°Π²Π½Π΅Π½ΠΈΡ Ρ ΠΈΠ·Π³ΠΎΡΠΎΠ²Π»Π΅Π½ΠΈΠ΅ΠΌ ΠΎΡΠ»ΠΈΠ²ΠΎΠΊ Π»ΠΈΡΡΡΠΌ Π² ΠΏΠ΅ΡΡΠ°Π½ΡΠ΅ ΡΠΎΡΠΌΡ, ΡΠΏΡΠ°Π²Π»Π΅Π½ΠΈΠ΅ ΡΠ΅ΠΏΠ»ΠΎΠ²ΡΠΌ ΡΠ΅ΠΆΠΈΠΌΠΎΠΌ ΠΎΡ Π»Π°ΠΆΠ΄Π΅Π½ΠΈΡ ΠΎΡΠ»ΠΈΠ²ΠΊΠΈ ΠΈ Π²ΠΎΠ·ΠΌΠΎΠΆΠ½ΠΎΡΡΡ ΠΌΠ΅Ρ Π°Π½ΠΈΠ·ΠΈΡΠΎΠ²Π°ΡΡ ΠΏΡΠΎΡΠ΅ΡΡ.
Literature
- ΠΠ°ΡΠΈΠ½ΠΎΠ² Π. Π. Β«ΠΠΎΠ΄ΠΎΠΎΡ Π»Π°ΠΆΠ΄Π°Π΅ΠΌΡΠ΅ Π²Π°Π³ΡΠ°Π½ΠΊΠΈ ΠΈ ΠΈΡ ΠΌΠ΅ΡΠ°Π»Π»ΡΡΠ³ΠΈΡΠ΅ΡΠΊΠΈΠ΅ Π²ΠΎΠ·ΠΌΠΎΠΆΠ½ΠΎΡΡΠΈΒ» , ΠΠΎΡΠΊΠ²Π°, Β«ΠΠ°ΡΠΈΠ½ΠΎΡΡΡΠΎΠ΅Π½ΠΈΠ΅Β» 1964