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N, N-Dimethyl-p-phenylenediamine

N, N-Dimethyl-p-phenylenediamine (dimethyl-p-phenylenediamine) is an organic substance derived from p-phenylenediamine with the formula (CH 3 ) 2 NC 6 H 4 NH 2 . Used in analytical chemistry and in the synthesis of dyes.

N, N-Dimethyl-p-phenylenediamine
Are common
Chem. formulaC₈H₁₂N₂
Thermal properties
T. melt.53 ° C
T. bale.262 ° C
Chemical properties
Solubility in watersoluble
Classification
Reg. CAS number
PubChem
Reg. EINECS number
Smiles
Inchi
Chebi
ChemSpider

Content

Physical and chemical properties

Melting point - 53 ° C, boiling point - 262 ° C. Soluble in water, chloroform, soluble in alcohol and ether [1] .

It has the ability to form various classes of dyes in the process of color photographic manifestation. In particular, with derivatives of naphthol forms indophenol dyes [2] :

  + 4 AgBr +  ⟶ {\ displaystyle {\ ce {->}}}     + 4 Ag + 4 HBr

Getting

Obtained by nitrosation of N, N-dimethylaniline and the subsequent reduction of N, N-dimethyl-4-nitrosoaniline with iron [1] .

Application

Apply:

  • in microscopy for the discovery of oxidases [1] ;
  • in analytical chemistry - for the determination of ozone in air, hydrogen sulfide , chlorine , bromine , vanadium sulfides [1] ;
  • in the production of dyes (sulfur and methylene blue ) [1] ;
  • in the photo: the substance is a color developing substance [2] [3] ( CD-8 , Color Developing Agent 8 ) [4] , but has not been used in practice in this role.

The reagent is usually produced in the form of salts having better solubility and shelf life: sulfate (cas 536-47-0), hydrochloride (cas 536-46-9) and oxalate (cas 62778-12-5).

Toxicity

Causes an allergy [1] .

Notes

  1. ↑ 1 2 3 4 5 6 Knunyants, 1983 , p. 183.
  2. ↑ 1 2 Eaton, 1965 , p. 54.
  3. ↑ Hunt, 2009 , p. 361.
  4. ↑ Konica .

Literature

  • Chemical Encyclopedic Dictionary / Ch. ed. Knunyants I.L. - M .: Sov. Encyclopedia, 1983.- 792 p.
  • Hunt R.V. G. Color reproduction / trans. A.E. Shadrin. - 6th ed .. - St. Petersburg. , 2009 .-- 887 p.
  • Eaton G. Photographic chemistry in black-and-white and color photograpy (neopr.) . - second edition. - NY: Morgan & Morgan, Inc., Publishers Hastings-on-Hudson, 1965.

Links

  • Nishijima T., Nishimura M. US Patent 5459014: Method for forming a photographic color image with a photographic material containing a hydroxy-phenyl derivative, using a chloride-containing color developer . Konica Corporation . Date of treatment May 21, 2017.
Source - https://ru.wikipedia.org/w/index.php?title=N,N-Dimethyl-p- phenylenediamine&oldid = 96548339


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