N, N-Dimethyl-p-phenylenediamine (dimethyl-p-phenylenediamine) is an organic substance derived from p-phenylenediamine with the formula (CH 3 ) 2 NC 6 H 4 NH 2 . Used in analytical chemistry and in the synthesis of dyes.
| N, N-Dimethyl-p-phenylenediamine | |
|---|---|
| Are common | |
| Chem. formula | C₈H₁₂N₂ |
| Thermal properties | |
| T. melt. | 53 ° C |
| T. bale. | 262 ° C |
| Chemical properties | |
| Solubility in water | soluble |
| Classification | |
| Reg. CAS number | |
| PubChem | |
| Reg. EINECS number | |
| Smiles | |
| Inchi | |
| Chebi | |
| ChemSpider | |
Content
Physical and chemical properties
Melting point - 53 ° C, boiling point - 262 ° C. Soluble in water, chloroform, soluble in alcohol and ether [1] .
It has the ability to form various classes of dyes in the process of color photographic manifestation. In particular, with derivatives of naphthol forms indophenol dyes [2] :
+ 4 AgBr + {\ displaystyle {\ ce {->}}} + 4 Ag + 4 HBr
Getting
Obtained by nitrosation of N, N-dimethylaniline and the subsequent reduction of N, N-dimethyl-4-nitrosoaniline with iron [1] .
Application
Apply:
- in microscopy for the discovery of oxidases [1] ;
- in analytical chemistry - for the determination of ozone in air, hydrogen sulfide , chlorine , bromine , vanadium sulfides [1] ;
- in the production of dyes (sulfur and methylene blue ) [1] ;
- in the photo: the substance is a color developing substance [2] [3] ( CD-8 , Color Developing Agent 8 ) [4] , but has not been used in practice in this role.
The reagent is usually produced in the form of salts having better solubility and shelf life: sulfate (cas 536-47-0), hydrochloride (cas 536-46-9) and oxalate (cas 62778-12-5).
Toxicity
Causes an allergy [1] .
Notes
- ↑ 1 2 3 4 5 6 Knunyants, 1983 , p. 183.
- ↑ 1 2 Eaton, 1965 , p. 54.
- ↑ Hunt, 2009 , p. 361.
- ↑ Konica .
Literature
- Chemical Encyclopedic Dictionary / Ch. ed. Knunyants I.L. - M .: Sov. Encyclopedia, 1983.- 792 p.
- Hunt R.V. G. Color reproduction / trans. A.E. Shadrin. - 6th ed .. - St. Petersburg. , 2009 .-- 887 p.
- Eaton G. Photographic chemistry in black-and-white and color photograpy (neopr.) . - second edition. - NY: Morgan & Morgan, Inc., Publishers Hastings-on-Hudson, 1965.
Links
- Nishijima T., Nishimura M. US Patent 5459014: Method for forming a photographic color image with a photographic material containing a hydroxy-phenyl derivative, using a chloride-containing color developer . Konica Corporation . Date of treatment May 21, 2017.