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Ammonium (mineral)

Ammonia (from arab. ﻧﺸﺎﺩﺭ (nūšādir) - “ ammonia ”) is a mineral consisting of ammonium chloride . The chemical formula is NH 4 Cl [1] .

Ammonia
FormulaNH 4 Cl
Molecular mass53.49
ImpurityFe, Br
IMA Statusvalid
IMA systematics ( Mills et al., 2009 )
ClassHalides
GroupSimple halides without water
Physical properties
ColorColorless, white, sometimes yellow or brown
Trait colorWhite
ShineGlass
TransparencyTransparent
Hardness1-2
Fragilitycutting
CleavageVery good, imperfect on {111}
KinkCrayfish
Separatenesstranslational slip with T {011}, t [001]
Density1,532 g / cm³
Radioactivity0 GRapi
Electrical conductivity1,60
Crystallographic properties
Point group4 / m 3 2 / m - cubic-hexaoctahedral
Space groupP m3m
SyngoniaCubic
Cell optionsa = 3.8759Å
Unit cell volumeV 57.47 ų
Twinby {111}, may be cyclic
Optical properties
Optical typeisotropic
Refractive indexn = 1,693
Birefringenceweak
Maximum birefringenceweak under mechanical deformation
Optical axis dispersionabsent
Pleochroismdoes not pleochroit

Content

  • 1 Structure
  • 2 Properties
  • 3 Morphology
  • 4 Origin
  • 5 Application
  • 6 notes
  • 7 References

Structure

Syngonia is cubic. It has a cubic-hexaoctahedral symmetry [2] . Close to halite and sylvin . During low-temperature crystallization, it differs in the body-centered structure of the crystal lattice (analogue of a zinc chloride crystal). May contain impurities of bromine and iodine [3] .

Properties

Colorless or white, with a glass sheen. Various coloring by impurities is possible (yellow-brown, gray [3] , reddish to brown). It is soluble in water (the solution has a burning caustic salty taste and a pungent odor) [4] . When heated under a blowtorch, it evaporates with the formation of smoke [3] .

Morphology

It is rare, usually in the form of sags, earthy deposits, crusts. Sometimes it forms massive clusters [3] , elongated skeletal crystals , clusters, dendrites [4] .

Origin

Product activity of volcanoes and hot springs [1] . It is also formed during the burning of coal seams or accumulations of debris, occasionally during the evaporation of groundwater in a hot climate. It is found in guano deposits. Often adjacent to native sulfur , when burning coal also with realgar , auripigment , , [5] .

Application

It is used as a chemical raw material [1] , as well as for soldering metals, gold alloying [3] .

Notes

  1. ↑ 1 2 3 Krishtofovich A. N. Geological dictionary / resp. ed. Spizharsky T.N. - “Book on demand.” - Moscow: GOSGEOLTEHIZDAT, 1955. - T. II M — I. - S. 66 .-- 449 p. - ISBN 9785458366540 .
  2. ↑ David Barthelmy. Salammoniac Mineral Data (Neopr.) . Mineralogy Database . webmineral.com. Date of treatment February 27, 2017.
  3. ↑ 1 2 3 4 5 Betekhtin A.G. Mineralogy / Ed. Krutova G.A. - Moscow: GOSGEOLIZDAT, 1950 .-- S. 326-332. - 957 s.
  4. ↑ 1 2 Salikhov V.S. Glossary of basic terms and concepts in geology: Textbook . - Chita: Transbaikal State University, 2015 .-- S. 75. - 143 p. - ISBN 978-5-9293-1276-2 .
  5. ↑ John W. Anthony et al. Sal ammoniac (Eng.) // Handbook of Mineralogy.

Links

  • Ammonia
  • Ammonia on Mindat.org
  • Ammonia on Webmineral.com
  • Ammonium on Mineralpro.ru
Source - https://ru.wikipedia.org/w/index.php?title=Nashatyr_(mineral)&oldid=95413402


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