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Silver trifluoroacetate

Silver trifluoroacetate is an inorganic compound, a salt of silver and trifluoroacetic acid with the formula CF 3 COOAg, colorless crystals, dissolved in water.

Silver trifluoroacetate
Are common
Systematic
name
Silver trifluoroacetate
Traditional namesTrifluoroacetic Silver
Chem. formulaCF 3 COOAg
Physical properties
conditioncolorless crystals
Molar mass220.88 g / mol
Thermal properties
T. decomp.260 ° C [1]
Chemical properties
Solubility in water170 18 g / 100 ml
Solubility in benzene7.2 20 g / 100 ml
Diethyl Solubility6.3 20 g / 100 ml
Solubility in trifluoroacetic acid17.9 30 g / 100 ml
Classification
Reg. CAS number2966-50-9
Reg. EINECS number

Content

Getting

  • The exchange reaction of sodium trifluoroacetate and silver nitrate, followed by extraction of silver trifluoroacetate with diethyl ether :
CF3COONa+AgNO3→CF3COOAg+NaNO3{\ displaystyle {\ mathsf {CF_ {3} COONa + AgNO_ {3} \ {\ xrightarrow {}} \ CF_ {3} COOAg + NaNO_ {3}}}}  
  • Dissolution of silver oxide in a solution of trifluoroacetic acid :
2CF3COOH+Ag2O→2CF3COOAg+H2O{\ displaystyle {\ mathsf {2CF_ {3} COOH + Ag_ {2} O \ {\ xrightarrow {}} \ 2CF_ {3} COOAg + H_ {2} O}}}  

Physical Properties

Silver trifluoroacetate forms colorless crystals.

It is soluble in water, ether and benzene , poorly soluble in chloroform .

Notes

  1. ↑ R. Szczęsny, E. Szłyk. Thermal decomposition of some silver (I) carboxylates under nitrogen atmosphere // J. Therm. Anal. Calorim .. - 2013 .-- T. 111 . - S. 1325–1330 . - DOI : 10.1007 / s10973-012-2485-1 . (inaccessible link)

Literature

  • Inorganic Synthesis Guide: 6 Vol. / Ed. Brower G. - M .: Mir, 1985 .-- T. 4 .-- 447 p.
  • Solubility Guide. - M.-L.: IAN USSR, 1961. - T. 1, book. 1. - 740 s.



Source - https://ru.wikipedia.org/w/index.php?title= Silver trifluoroacetate&oldid = 100537880


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Clever Geek | 2019