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Silver chlorite

Silver chlorite is an inorganic compound, a salt of silver and perchloric acid with the formula AgClO 2 , yellow crystals, slightly soluble in water.

Silver chlorite
Are common
Systematic
name
Silver chlorite
Traditional namesSilver chloride
Chem. formulaAgClO 2
Physical properties
conditionyellow crystals
Molar mass175.32 g / mol
Density4.6 g / cm³
Thermal properties
T. decomp.105 ° C
Chemical properties
Solubility in water0.55 25 g / 100 ml
Classification
Reg. CAS number7783-91-7
Smiles

Content

Getting

  • The exchange reaction of solutions of sodium chlorite and silver nitrate :
NaClO2+AgNO3→90-95oCAgClO2↓+NaNO3{\ displaystyle {\ mathsf {NaClO_ {2} + AgNO_ {3} \ {\ xrightarrow {90-95 ^ {o} C}} \ AgClO_ {2} \ downarrow + NaNO_ {3}}}}  

Physical Properties

Silver chlorite forms yellow crystals of rhombic syngony , space group P cca , cell parameters a = 0.607 nm , b = 0.668 nm , c = 0.613 nm , Z = 4 [1] .

It is slightly soluble in water, p PR = 3.7.

At a temperature of 105 ° C decomposes with an explosion.

Notes

  1. ↑ J. Cooper, RE Marsh. On the structure of AgClO 2 // Acta Cryst .. - 1961. - T. 14 . - S. 202-203 . - DOI : 10.1107 / S0365110X61000693 .

Literature

  • CRC Handbook of Chemistry and Physics . - 89th Edition. - Taylor and Francis Group, LLC, 2008-2009.



Source - https://ru.wikipedia.org/w/index.php?title=Silver Chlorite&oldid = 80372822


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Clever Geek | 2019