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Dis telluride

Disodium silver telluride is a binary inorganic compound of silver and tellurium with the formula Ag 2 Te, gray or black crystals, it does not dissolve in water.

Dis telluride
General
Systematic
name
Dis telluride
Traditional namesTellurium silver
Chem. formulaAg 2 Te
Physical properties
conditiongray crystals
Molar mass343.34 g / mol
Density8.4; 8.5 g / cm³
Thermal properties
T. melt.955; 960 ° C
Enthalpy of Education-18.1 [1] kJ / mol
Classification
Reg. CAS number12002-99-2
PubChem
Reg. EINECS number
Smiles
Inchi
ChemSpider

Content

  • 1 Receiving
  • 2 Physical properties
  • 3 notes
  • 4 Literature

Getting

  • In nature, the Hessite mineral Ag 2 Te with impurities Au , Pb is found [2] .
  • Heating stoichiometric amounts of pure substances:
2Ag+Te→960oCAg2Te{\ displaystyle {\ mathsf {2Ag + Te \ {\ xrightarrow {960 ^ {o} C}} \ Ag_ {2} Te}}}  

Physical Properties

Disodium silver telluride forms gray or black crystals of several modifications:

  • α-Ag 2 Te, monoclinic syngony , space group P 2 1 / c , cell parameters a = 0.652 nm , b = 0.615 nm , c = 0.611 nm , β = 61.25 ° , exists at temperatures below 145 ° C;
  • β-Ag 2 Te, cubic syngony , space group F m 3 m , cell parameters a = 0.6595 nm , Z = 4 , exists at a temperature of 145-802 ° С;
  • γ-Ag 2 Te, cubic syngony , space group F m 3 m , cell parameters a = 0.529 nm , Z = 2 , exists at temperatures above 802 ° C [3] [4] .

Not soluble in water.

The compound melts congruently at a temperature of 960 ° C.

Notes

  1. ↑ P. Franke, D. Neuschütz. Ag-Te (Silver - Tellurium). Thermodynamic Properties of Inorganic Materials // Landolt-Börnstein - Group IV Physical Chemistry. - 2007.- T. 19B5 . - S. 1-4 . - DOI : 10.1007 / 978-3-540-45280-5_16 .
  2. ↑ Hessit. Material from GeoWiki, an open encyclopedia on Earth sciences.
  3. ↑ State Diagrams of Double Metal Systems / Ed. N.P. Lyakisheva. - M .: Mechanical Engineering, 1996. - T. 1. - 992 p. - ISBN 5-217-02688-X .
  4. ↑ B. Predel. Ag-Te (Silver-Tellurium) // Landolt-Börnstein - Group IV Physical Chemistry. - 1991 .-- T. 5a . - S. 1-6 . - DOI : 10.1007 / 10000866_74 .

Literature

  • Chemistry Handbook / Editorial: Nikolsky B.P. et al. - 2nd ed., rev. - M.-L.: Chemistry, 1966. - T. 1. - 1072 p.
  • Chemistry Handbook / Editorial: Nikolsky B.P. et al. - 3rd ed., rev. - L .: Chemistry, 1971. - T. 2. - 1168 p.
  • CRC Handbook of Chemistry and Physics . - 89th Edition. - Taylor and Francis Group, LLC, 2008-2009.



Source - https://ru.wikipedia.org/w/index.php?title=Telluride_diserebro&oldid=80370578


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