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Dithitan Sulfide

Dititane sulfide is a binary inorganic compound of titanium and sulfur with the formula Ti 2 S, crystals.

Dithitan Sulfide
Are common
Systematic
name
Dithitan Sulfide
Traditional namesTitanium sulphide
Chem. formulaTi 2 S
Physical properties
conditioncrystals
Molar mass127.80 g / mol
Density4.8 g / cm³
Thermal properties
T.1305 ° C

Getting

  • Heating a stoichiometric mixture of pure substances:
2Ti+S→1410oCTi2S{\ displaystyle {\ mathsf {2Ti + S \ {\ xrightarrow {1410 ^ {o} C}} \ Ti_ {2} S}}}  

Physical Properties

Dithitan sulfide forms rhombic syngony crystals, space group Pnnm , cell parameters a = 1.135 nm , b = 1.406 nm , c = 0.332 nm , Z = 12 [1] [2] [3] [4] .

The compound is formed by a peritectic reaction at a temperature of 1410 ° C.

Notes

  1. ↑ State Diagrams of Double Metallic Systems / Ed. N. P. Lyakishev. - M .: Engineering, 2000. - T. 3 Book 2. - 448 p. - ISBN 5-217-02932-3 .
  2. ↑ B. Predel. S-Ti (Sulfur-Titanium) // Landolt-Börnstein - Group IV Physical Chemistry. - 1998 .-- T. 5J . - S. 1-4 . - DOI : 10.1007 / 10551312_2665 .
  3. ↑ JL Murray. The S − Ti (Sulfur-Titanium) system // Bulletin of Alloy Phase Diagrams. - 1986. - T. 7 , No. 2 . - S. 156-163 . - DOI : 10.1007 / BF02881555 .
  4. ↑ JP Owens, BR Conrad, NF Franzen. The crystal structure of Ti 2 S // Acta Cryst .. - 1967. - T. 23 . - S. 77-82 . - DOI : 10.1107 / S0365110X67002154 .


Source - https://ru.wikipedia.org/w/index.php?title=Dithitan sulfide&oldid = 87794170


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Clever Geek | 2019