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Disulfide diethesia

Diethesia disulfide is an inorganic compound of sulfur and cesium with the formula Cs 2 S 2 , dark red crystals, forms a crystalline hydrate .

Disulfide diethesia
Are common
Systematic
name
Disulfide diethesia
Traditional namesCesium Sulfur
Chem. formulaCs 2 S 2
Physical properties
conditiondark red crystals
Molar mass329.94 g / mol
Density3.1 g / cm³
Thermal properties
T. melt.≈460 ° C

Getting

  • Fusion of stoichiometric amounts of pure substances:
2Cs+2S→460oCCs2S2{\ displaystyle {\ mathsf {2Cs + 2S \ {\ xrightarrow {460 ^ {o} C}} \ Cs_ {2} S_ {2}}}  

Physical Properties

Diethesia disulfide forms dark red rhombic crystals, space group I mmm , cell parameters a = 0.6992 nm , b = 0.9615 nm , c = 0.5232 nm , Z = 2 [1] [2] [3] [4] .

The compound melts congruently at a temperature of 460 ° C.

Forms crystalline hydrate of Cs 2 S 2 • H 2 O.

Notes

  1. ↑ State Diagrams of Double Metallic Systems / Ed. N. P. Lyakishev. - M .: Metallurgy, 1997. - T. 2. - 1024 p. - ISBN 5-217-01569-1 .
  2. ↑ B. Predel. Cs-S (Cesium-Sulfur) // Landolt-Börnstein - Group IV Physical Chemistry. - 1994. - V. 5d . - S. 1-2 . - DOI : 10.1007 / 10086090_1059 .
  3. ↑ J. Sangster, AD Pelton. The Cs-S (Cesium-Sulfur) system // Journal of Phase Equilibria. - 1997. - Vol. 18 , No. 1 . - p . 78-81 . - DOI : 10.1007 / BF02646760 .
  4. ↑ P. Böttcher. Zur synthese und struktur von Cs 2 S 2 // Journal of the Less Common Metals. - 1979. - Vol . 63 , No. 1 . - p . 99-103 . - DOI : 10.1016 / 0022-5088 (79) 90212-1 .



Source - https://ru.wikipedia.org/w/index.php?title=Disulfide_dithesia&oldid=87632964


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