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Dysesia hexasulphide

Dicesium hexasulfide is an inorganic compound of sulfur and cesium with the formula Cs 2 S 6 , red crystals.

Dysesia hexasulphide
Are common
Systematic
name
Dysesia hexasulphide
Traditional namesCesium sulphide
Chem. formulaCs 2 s 6
Physical properties
conditionred crystals
Molar mass458.20 g / mol
Density3.1 g / cm³
Thermal properties
T. melt.186 ° C

Getting

  • Fusion of stoichiometric amounts of pure substances:
2Cs+6S→186oCCs2S6{\ displaystyle {\ mathsf {2Cs + 6S \ {\ xrightarrow {186 ^ {o} C}} \ Cs_ {2} S_ {6}}}} {\displaystyle {\mathsf {2Cs+6S\ {\xrightarrow {186^{o}C}}\ Cs_{2}S_{6}}}}

Physical Properties

Dysesia hexasulfide forms red crystals of triclinic syngony , space group P 1 , cell parameters a = 1.153 nm , b = 0.918 nm , c = 0.467 nm , α = 89.22 ° , β = 95.2 ° , γ = 95.13 ° , Z = 2 [1] [2] [3] [4] .

The compound melts congruently at a temperature of 186 ° C.

Notes

  1. ↑ State Diagrams of Double Metal Systems / Ed. N.P. Lyakisheva. - M .: Metallurgy, 1997 .-- T. 2 .-- 1024 p. - ISBN 5-217-01569-1 .
  2. ↑ B. Predel. Cs-S (Caesium-Sulfur) // Landolt-Börnstein - Group IV Physical Chemistry. - 1994 .-- T. 5d . - S. 1-2 . - DOI : 10.1007 / 10086090_1059 .
  3. ↑ J. Sangster, AD Pelton. The Cs-S (Cesium-Sulfur) system // Journal of Phase Equilibria. - 1997. - T. 18 , No. 1 . - S. 78-81 . - DOI : 10.1007 / BF02646760 .
  4. ↑ Hordvik A., Sletten E. Least squares refinement of the molecular structure of cesium hexasulfide // Acta Chemica Scandinavica. - 1968 .-- T. 22 . - S. 3029-3030 . - DOI : 10.3891 / acta.chem.scand.22-30-30 .


Source - https://ru.wikipedia.org/w/index.php?title= Hexasulfide_dicezia&oldid = 101154349


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