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Trisradiazotepentoxide

Trisradiazotepentoksid - inorganic compound, sulfur , oxygen and nitrogen with the formula S 3 N 2 O 5 , colorless crystals, decomposed in water.

Trisradiazotepentoxide
Are common
Systematic
name
Trisradiazotepentoxide
Chem. formulaS 3 N 2 O 5
Physical properties
conditioncolorless crystals
Molar mass204.21 g / mol
Density2.2 g / cm³

Content

Getting

  • Addition of sulfur trioxide to tetraser tetranitride :
SfourNfour+6SO3→2S3N2Ofive+fourSO2{\ displaystyle {\ mathsf {S_ {4} N_ {4} + 6SO_ {3} \ {\ xrightarrow {}} \ 2S_ {3} N_ {2} O_ {5} + 4SO_ {2}}}  
the compound is purified by sublimation in a vacuum of 70-80 ° C.

Physical Properties

Trisradiazapentoxide forms colorless monoclinic crystals, space group P 2 1 / c , cell parameters a = 0.8227 nm , b = 0.9958 nm , c = 0.7841 nm , β = 112.4 ° , Z = 4 [1 ] .

It is dissolved in organic solvents.

Stable in the dry state, reacts violently with traces of moisture.

Notes

  1. ↑ Rodek E., Amin N., Roesky HW Reaktionen und Roentgenkristallstrukturanalyse von S 3 N 2 O 5 // Zeitschrift fuer Anorganische und Allgemeine Chemie. - 1979. - T. 457 . - p . 123-126 .

Literature

  • Manual on inorganic synthesis: B 6 tons / Ed. Brower G. .. - M .: Mir, 1985. - T. 2. - 338 p.
  • Nekrasov B.V. Fundamentals of General Chemistry .. - 3rd ed., Rev. and additional .. - M .: "Chemistry", 1973. - T. 1. - 656 p.


Source - https://ru.wikipedia.org/w/index.php?title=Treeradiazapentoxide and olold = 80371872


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