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Isocyanate sulfonyl chloride

Sulfonyl chloride isocyanate is an inorganic compound, isocyanolic chloroanhydride of sulfuric acid with the formula ClSO 2 NCO, a colorless liquid.

Isocyanate sulfonyl chloride
Are common
Systematic
name
Isocyanate sulfonyl chloride
Traditional namesChlorosulfonyl isocyanate
Chem. formulaClSO 2 NCO
Rac formulaSO 2 NCOCl
Physical properties
conditioncolorless liquid
Molar mass141.53 g / mol
Density1,626 g / cm³
Thermal properties
T. melt.-44 ° C
T. Kip.106-107 ° C
Classification
Reg. CAS number1189-71-5

Getting

  • The reaction of sulfur trioxide and cyan chloride :
2SO3+ClCN→-five÷-15oCClS2OfiveNCO{\ displaystyle {\ mathsf {2SO_ {3} + ClCN \ {\ xrightarrow {-5 \ div -15 ^ {o} C}} \ ClS_ {2} O_ {5} NCO}}}  
ClS2OfiveNCO+ClCN→120-125oC2ClSO2NCO{\ displaystyle {\ mathsf {ClS_ {2} O_ {5} NCO + ClCN \ {\ xrightarrow {120-125 ^ {o} C}} \ 2ClSO_ {2} NCO}}}  

Physical Properties

The sulfonyl chloride isocyanate forms a colorless volatile liquid with a suffocating odor.

With water reacts with an explosion.

It is dissolved in carbon tetrachloride , benzene , cyclohexane , diethyl ether .

Literature

  • Manual on inorganic synthesis: B 6 tons / Ed. Brower G. .. - M .: Mir, 1985. - T. 2. - 338 p.


Source - https://ru.wikipedia.org/w/index.php?title=Isocyanate_sulfonylchloride&oldid=80365206


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