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Selenide Dithallium

Ditallium selenide is a binary inorganic compound of thallium and selenium with the formula Tl 2 Se, crystals.

Selenide Dithallium
Are common
Systematic
name
Selenide Dithallium
Traditional namesSelenium Thallium
Chem. formulaTl 2 Se
Physical properties
conditioncrystals
Molar mass487.73 g / mol
Density8.1 g / cm³
Thermal properties
T. melt.390 ° C
Enthalpy of Education31.3 [1] kJ / mol
Classification
Reg. CAS number15572-25-5

Getting

  • Fusion of stoichiometric amounts of pure substances:
2Tl+Se→390oCTl2Se{\ displaystyle {\ mathsf {2Tl + Se \ {\ xrightarrow {390 ^ {o} C}} \ Tl_ {2} Se}}}  

Physical Properties

Dithallium selenide forms tetragonal crystal crystals, space group P 4 / ncc , cell parameters a = 0.854 nm , c = 0.271 nm , Z = 2 [2] [3] [4] [5] .

The compound melts congruently at a temperature of 390 ° C.

Notes

  1. ↑ VP Vasilyev, VS Minaev, LP Batyunya. Thermodynamic Properties, Phase Diagrams and Glassformation of Thallium Chalcogenides // Chalcogenide Letters. - 2013. - T. 10 , No. 11 . - S. 485-507 .
  2. ↑ State Diagrams of Double Metal Systems / Ed. N.P. Lyakisheva. - M .: Engineering, 2000. - T. 3 Book 2. - 448 p. - ISBN 5-217-02932-3 .
  3. ↑ B. Predel. Se-Tl (Selenium-Thallium) // Landolt-Börnstein - Group IV Physical Chemistry. - 1998 .-- T. 5J . - S. 1-2 . - DOI : 10.1007 / 10551312_2720 .
  4. ↑ P. Franke, D. Neuschütz. Se-Tl // Landolt-Börnstein - Group IV Physical Chemistry. - 2006. - T. 19B4 . - S. 1-3 . - DOI : 10.1007 / 10757285_66 .
  5. ↑ H. Okamoto. Se-Tl (Selenium-Thallium) // Journal of Phase Equilibria and Diffusion. - 2011. - T. 32 , No. 6 . - S. 570-571 . - DOI : 10.1007 / s11669-011-9954-2 .


Source - https://ru.wikipedia.org/w/index.php?title= Selenide_dithallium&oldid = 91265807


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