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Triselenide ditoria

Trielenide ditorium is a binary inorganic compound of thorium and selenium with the formula Th 2 Se 3 , dark gray crystals.

Triselenide ditoria
Are common
Systematic
name
Triselenide ditoria
Traditional namesSeleny Thorium
Chem. formulaTh 2 se 3
Physical properties
conditiondark gray crystals
Molar mass700.96 g / mol
Density8.2 g / cm³
Thermal properties
T.1490 ° C

Content

Getting

  • Reaction of pure substances in an inert atmosphere:
2Th+3Se→1490oCTh2Se3{\ displaystyle {\ mathsf {2Th + 3Se \ {\ xrightarrow {1490 ^ {o} C}} \ Th_ {2} Se_ {3}}}  

Physical Properties

Trithelenide ditorium forms dark gray rhombic crystals, space group P nma , cell parameters a = 1.1354 nm , b = 1.1575 nm , c = 0.427 nm , Z = 4 , the structure of the type of disulfide trisulfide Sb 2 S 3 [1 ] [2] .

The compound is formed by the peritectic reaction at a temperature of 1490 ° C.

Chemical Properties

  • Oxidized when heated in air [3] :
Th2Se3+fiveO2→T2ThO2+3SeO2{\ displaystyle {\ mathsf {Th_ {2} Se_ {3} + 5O_ {2} \ {\ xrightarrow {T}} \ 2ThO_ {2} + 3SeO_ {2}}}}  

Notes

  1. ↑ State Diagrams of Double Metallic Systems / Ed. N. P. Lyakishev. - M .: Mashinostroenie, 2000. - T. 3 Book 2. - 448 p. - ISBN 5-217-02932-3 .
  2. ↑ B. Predel. Se-Th (Selenium-Thorium) // Landolt-Börnstein - Group IV Physical Chemistry. - 1998. - T. 5J . - S. 1-2 . - DOI : 10.1007 / 10551312_2718 .
  3. ↑ David Brown, Horst Wedemeyer. Th Thium: Compounds with S, Se, Te and B. - Springer Science & Business Media, 2013. - p. 95. - 149 p. - ISBN 9783662063422 .


Source - https://ru.wikipedia.org/w/index.php?title=Treeleden_ditorium&oldid=80371851


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