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Iridium Diselenide

Iridium dyslenide is a binary inorganic compound of iridium and selenium with the formula IrSe 2 , crystals.

Iridium Diselenide
General
Systematic
name
Iridium Diselenide
Traditional namesSelenium iridium
Chem. formulaIrse 2
Physical properties
conditioncrystals
Molar mass350.14 g / mol
Density10.0 g / cm³
Classification
Reg. CAS number12030-55-6
PubChem

Content

  • 1 Receiving
  • 2 Physical properties
  • 3 See also
  • 4 notes

Getting

  • Fusion of stoichiometric amounts of pure substances:
Ir+2Se→TIrSe2{\ displaystyle {\ mathsf {Ir + 2Se \ {\ xrightarrow {T}} \ IrSe_ {2}}}}  

Physical Properties

Iridium dislenide forms rhombic syngony crystals, space group P nma , cell parameters a = 2.094 nm , b = 0.374 nm , c = 0.593 nm , Z = 8 [1] [2] [3] .

At a temperature of ≈6 K it transforms into a superconducting state [4]

See also

  • Hideo Hosono

Notes

  1. ↑ State Diagrams of Double Metal Systems / Ed. N.P. Lyakisheva. - M .: Engineering, 2001. - T. 3 Book 1. - 972 p. - ISBN 5-217-02843-2 .
  2. ↑ B. Predel. Ir-Se (Iridium-Selenium) // Landolt-Börnstein - Group IV Physical Chemistry. - 1997. - T. 5G . - S. 1 . - DOI : 10.1007 / 10506626_1810 .
  3. ↑ LB Barricelli. The crystal structure of iridium diselenide // Acta Cryst .. - 1958.- T. 11 . - S. 75-79 . - DOI : 10.1107 / S0365110X58000219 .
  4. ↑ Jiangang Guo, Yanpeng Qi, Satoru Matsuishi ‡, Hideo Hosono . T c Maximum in Solid Solution of Pyrite IrSe 2 –RhSe 2 Induced by Destabilization of Anion Dimers // J. Am. Chem. Soc .. - 2012. - T. 134 , No. 49 . - S. 20001–20004 . - DOI : 10.1021 / ja309724w .


Source - https://ru.wikipedia.org/w/index.php?title=Direlenide_iridium&oldid=92165177


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