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Barium Diselenide

Barium dyslenide is a binary inorganic compound of barium and selenium with the formula BaSe 2 , crystals.

Barium Diselenide
General
Systematic
name
Barium Diselenide
Traditional namesBipartite barium
Chem. formulaBase 2
Physical properties
conditioncrystals
Molar mass295.25 g / mol
Density4.9 g / cm³
Thermal properties
T. decomp.840; 870 ° C

Content

  • 1 Receiving
  • 2 Physical properties
  • 3 notes
  • 4 See also

Getting

  • Fusion of stoichiometric amounts of pure substances:
Ba+2Se→500-700oCBaSe2{\ displaystyle {\ mathsf {Ba + 2Se \ {\ xrightarrow {500-700 ^ {o} C}} \ BaSe_ {2}}}}  

Physical Properties

Barium dislenide forms monoclinic syngony crystals, space group C c , cell parameters a = 0.9820 nm , b = 0.4929 nm , c = 0.9335 nm , β = 118.48 ° , Z = 4 , barium disulfide type structure BaS 2 [1] [2] [3] .

The compound is formed by a peritectic reaction at a temperature of 870 ° C [1] ( 840 ° C [3] ).

Notes

  1. ↑ 1 2 State Diagrams of Double Metal Systems / Ed. N.P. Lyakisheva. - M .: Mechanical Engineering, 1996. - T. 1. - 992 p. - ISBN 5-217-02688-X .
  2. ↑ Hulliger F., Siegrist T. The crystal structures of BaSe 2 and BaSe 3 // Zeitschrift fuer Naturforschung, Teil B. Anorganische Chemie, Organische Chemie. - 1981. - T. 36 . - S. 14-15 .
  3. ↑ 1 2 B. Predel. Ba-Se (Barium-Selenium) // Landolt-Börnstein - Group IV Physical Chemistry. - 1992. - T. 5b . - S. 1-2 . - DOI : 10.1007 / 10040476_448 .

See also

  • Barium Selenide
  • Barium triselide


Source - https://ru.wikipedia.org/w/index.php?title=D bariumdelenide&oldid = 80364238


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