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Trisvincide

Trisvincium sodium is a binary inorganic compound of lead and sodium with the formula NaPb 3 , crystals.

Trisvincide
Are common
Systematic
name
Trisvincide
Traditional namesSodium Tritene
Chem. formulaNaPb 3
Rat formulaPb 3 Na
Physical properties
conditioncrystals
Molar mass644.59 g / mol
Density9.1 g / cm³
Thermal properties
T. melt.320 ° C
Classification
Reg. CAS number12058-62-7

Getting

  • Fusion of stoichiometric amounts of pure substances:
3Pb+Na→320oCNaPb3{\ displaystyle {\ mathsf {3Pb + Na \ {\ xrightarrow {320 ^ {o} C}} \ NaPb_ {3}}}}  

Physical Properties

Trisvincium sodium forms crystals of cubic syngony , space group P m 3 m , cell parameters a = 0.4888 nm , Z = 1 , structure like tri - gold AuCu 3 [1] [2] .

The compound melts congruently at a temperature of 320 ° C [1] .

At a temperature of 5.62 K, the compound goes into a superconducting state [3] .

The compound is enriched in sodium and has a homogeneity region of 27 ÷ 32.5 at.% Sodium.

Notes

  1. ↑ 1 2 State Diagrams of Double Metal Systems / Ed. N.P. Lyakisheva. - M .: Engineering, 2001. - T. 3 Book 1. - 972 p. - ISBN 5-217-02843-2 .
  2. ↑ B. Predel. Na-Pb (Sodium-Lead) // Landolt-Börnstein - Group IV Physical Chemistry. - 1997. - T. 5H . - S. 1-5 . - DOI : 10.1007 / 10522884_2154 .
  3. ↑ Charles K. Poole, Horacio A. Farach, Richard J. Creswick. Handbook of Superconductivity . - Academic Press, 1999 .-- S. 194. - 693 p. - ISBN 9780080533216 .


Source - https://ru.wikipedia.org/w/index.php?title=Tricvinosodium &oldid = 80371788


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