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Pentas lead lead

Pentas lead lead is an inorganic binary compound of lead and barium with the formula Ba 3 Pb 5 , crystals.

Pentas lead lead
Are common
Systematic
name
Pentas lead lead
Traditional namesTribariopenta lead
Chem. formulaBa 3 Pb 5
Rat formulaPb 5 Ba 3
Physical properties
conditioncrystals
Molar mass1447.98 g / mol
Density8.3 g / cm³
Thermal properties
T. decomp.726 ° C

Getting

  • Fusion of stoichiometric amounts of pure substances:
fivePb+3Ba→726oCBa3Pbfive{\ displaystyle {\ mathsf {5Pb + 3Ba \ {\ xrightarrow {726 ^ {o} C}} \ Ba_ {3} Pb_ {5}}}}  

Physical Properties

Penta lead lead forms rhombic syngony crystals, space group C mcm , cell parameters a = 1.1148 nm , b = 0.9049 nm , c = 1.1368 nm , Z = 4 , pentapalladium triplutonium type structure Pu 3 Pd 5 [1] [2 ] ] [3] [4] .

The compound is formed by a peritectic reaction at a temperature of 726 ° C

Notes

  1. ↑ State Diagrams of Double Metal Systems / Ed. N.P. Lyakisheva. - M .: Mechanical Engineering, 1996. - T. 1. - 992 p. - ISBN 5-217-02688-X .
  2. ↑ B. Predel. Ba-Pb (Barium-Lead) // Landolt-Börnstein - Group IV Physical Chemistry. - 1992. - T. 5b . - S. 1-2 . - DOI : 10.1007 / 10040476_437 .
  3. ↑ H. Okamoto. Ba-Pb (Barium-Lead) // Journal of Phase Equilibria and Diffusion. - 2008. - T. 29 , No. 3 . - S. 293-293 . - DOI : 10.1007 / s11669-008-9310-3 .
  4. ↑ Giacomo Bruzzone, Enrico Franceschi. Equilibrium phase diagram and crystal structures of the intermediate phases of the Ba-Pb binary system // Journal of the Less Common Metals. - 1977. - T. 52 , No. 2 . - S. 211-216 . - DOI : 10.1016 / 0022-5088 (77) 90003-0 .


Source - https://ru.wikipedia.org/w/index.php?title= Penta lead tribaria &oldid = 80368503


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