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Lead cyanide (II)

Lead (II) cyanide is an inorganic compound, a salt of lead metal and hydrocyanic acid with the formula Pb (CN) 2 , light yellow crystals, slightly soluble in water. Like all cyanides, it is very toxic.

Lead cyanide
Are common
Systematic
name
Lead cyanide (II)
Traditional namesCyanide lead
Chem. formulaPb (CN) 2
Physical properties
conditionlight yellow crystals
Molar mass259.23 g / mol
Chemical properties
Solubility in water0.01 [1] g / 100 ml
Classification
Reg. CAS number592-05-2
Reg. EINECS number209-742-1
Smiles
Security
MPC0.01 mg / m³
Toxicity

extremely toxic; strongest poison

Hazard TT.svg
NFPA 704
NFPA 704.svg
0
four
0

Getting

  • The action of potassium cyanide on a solution of lead (II) salt [2] :
Pb(NO3)2+2KCN→Pb(CN)2↓+2KNO3{\ displaystyle {\ mathsf {Pb (NO_ {3}) _ {2} + 2KCN \ {\ xrightarrow {}} \ Pb (CN) _ {2} \ downarrow + 2KNO_ {3}}}} {\displaystyle {\mathsf {Pb(NO_{3})_{2}+2KCN\ {\xrightarrow {}}\ Pb(CN)_{2}\downarrow +2KNO_{3}}}}

Physical Properties

Lead (II) cyanide forms light yellow crystals.

It is slightly soluble in cold water, soluble in hot [3] [4] .

Chemical Properties

  • It is dissolved in an excess of cyanides :
2KCN+Pb(CN)2→K2[Pb(CN)four]{\ displaystyle {\ mathsf {2KCN + Pb (CN) _ {2} \ rightarrow K_ {2} [Pb (CN) _ {4}]}}} {\displaystyle {\mathsf {2KCN+Pb(CN)_{2}\rightarrow K_{2}[Pb(CN)_{4}]}}}

Application

  • Electrolyte component in electroplating .
  • Insecticide [5] .

Toxicity

 

Like all lead and cyanide compounds, lead cyanide is the strongest poison.

Notes

  1. ↑ Solubility of inorganic compounds in mixed and non-aqueous solvents
  2. ↑ Solozhenkin P. M. The role of lead cations in the process of gold leaching and cementation . - 2005.
  3. ↑ Chemist's Handbook / Editorial: Nikolsky B.P. et al. - 3rd ed., rev. - L .: Chemistry, 1971. - T. 2. - 1168 p.
  4. ↑ CRC Handbook of Chemistry and Physics . - 89th Edition. - Taylor and Francis Group, LLC, 2008-2009.
  5. ↑ Chemical Encyclopedic Dictionary / Editorial board: Knunyants I.L. et al. - M .: Soviet Encyclopedia, 1983. - 792 p.

Literature

  • Polyansky N.G. Lead. Analytical chemistry of elements. - M: Nauka, 1986 .-- 357 p.
Source - https://ru.wikipedia.org/w/index.php?title= Lead cyanide ( II)&oldid = 100317567


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