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Pentatalliumtrice

Pentatallium trisiarium - binary inorganic compound, intermetallic samarium and thallium with the formula Sm 5 Tl 3 , crystals.

Pentatalliumtrice
Are common
Systematic
name
Pentatalliumtrice
Traditional namesTrisaria Pentatallium
Chem. formulaSm 3 Tl 5
Rac formulaTl 5 Sm 3
Physical properties
conditioncrystals
Molar mass1473.00 g / mol
Density11.3 g / cm³
Thermal properties
T.940 ° C

Getting

  • Fusion of stoichiometric amounts of pure substances:
3Sm+fiveTl→940oCSm3Tlfive{\ displaystyle {\ mathsf {3Sm + 5Tl \ {\ xrightarrow {940 ^ {o} C}} \ Sm_ {3} Tl_ {5}}}}  

Physical Properties

Pentatallium trisiamary forms crystals of the rhombic syngony , space group C mcm , cell parameters a = 1.011 nm , b = 0.8155 nm , c = 1.044 nm , Z = 4 , the structure of the pentapalladium triplutonium type Pu 3 Pd 5 [1] [2] [3] .

The compound is formed by a peritectic reaction at a temperature of 940 ° C [3]

Notes

  1. ↑ State Diagrams of Double Metallic Systems / Ed. N. P. Lyakishev. - M .: Mashinostroenie, 2000. - T. 3 Book 2. - 448 p. - ISBN 5-217-02932-3 .
  2. ↑ B. Predel. Sm-Tl (Samarium-Thallium) // Landolt-Börnstein - Group IV Physical Chemistry. - 1998. - T. 5J . - S. 1-2 . - DOI : 10.1007 / 10551312_2752 .
  3. ↑ 1 2 S. Delfino, A. Saccone, G. Borzone, R. Ferro. Thallium alloys of the rare earths: Sm — TI Phase II: // Zeitschrift für anorganische und allgemeine Chemie. - 1983. - V. 503 , № 8 . - p . 184-192 . - DOI : 10.1002 / zaac.19835030819 .


Source - https://ru.wikipedia.org/w/index.php?title=Pentatalliumtrisamarium&oldid=91264851


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Clever Geek | 2019