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Disamarium antimonide

Disamarium antimonide is a binary inorganic compound of samarium and antimony with the formula Sm 2 Sb, crystals.

Disamarium antimonide
Are common
Systematic
name
Disamarium antimonide
Traditional namesAntimony Samaria
Chem. formulaSm 2 sb
Rat formulaSbsm 2
Physical properties
conditioncrystals
Molar mass422.48 g / mol
Density8.0 g / cm³
Thermal properties
T. decomp.≈1300 ° C
Classification
Reg. CAS number93844-14-5

Getting

  • Heating of pure substances in vacuum :
2Sm+Sb→1300oCSm2Sb{\ displaystyle {\ mathsf {2Sm + Sb \ {\ xrightarrow {1300 ^ {o} C}} \ Sm_ {2} Sb}}}  

Physical Properties

Disamarium antimonide forms tetragonal syngony crystals, space group I 4 / mmm , cell parameters a = 0.4468 ÷ 0.4478 nm , c = 1.746 ÷ 1.745 nm , Z = 4 structure of the dilantan antimonide type La 2 Sb [1] [2] [3] .

The compound is formed by a peritectic reaction at a temperature of ≈1300 ° С [1] .

Notes

  1. ↑ 1 2 State Diagrams of Double Metal Systems / Ed. N.P. Lyakisheva. - M .: Engineering, 2000. - T. 3 Book 2. - 448 p. - ISBN 5-217-02932-3 .
  2. ↑ B. Predel. Sb-Sm (Antimony-Samarium) // Landolt-Börnstein - Group IV Physical Chemistry. - 1998 .-- T. 5J . - S. 1-2 . - DOI : 10.1007 / 10551312_2677 .
  3. ↑ H. Okamoto. Sb-Sm (Antimony-Samarium) // Journal of Phase Equilibria. - 2000. - T. 21 , No. 4 . - S. 414-415 . - DOI : 10.1361 / 105497100770340002 .



Source - https://ru.wikipedia.org/w/index.php?title=Antimonid_disamaria&oldid=88750735


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