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Samaridinickel

Samarium nickel is a binary inorganic compound of nickel and samarium with the formula Ni 2 Sm, crystals.

Samaridinickel
General
Systematic
name
Samaridinickel
Traditional namesDinickelsamarium
Chem. formulaNi 2 Sm
Rat formulaSmni 2
Physical properties
conditioncrystals
Molar mass267.75 g / mol
Density9.4 g / cm³
Thermal properties
T. decomp.1034 ° C
Enthalpy of Education-108 [1] kJ / mol
Classification
Reg. CAS number12201-95-5

Getting

  • Fusion of stoichiometric amounts of pure substances:
2Ni+Sm→1034oCNi2Sm{\ displaystyle {\ mathsf {2Ni + Sm \ {\ xrightarrow {1034 ^ {o} C}} \ Ni_ {2} Sm}}}  

Physical Properties

Samarium nickel forms crystals of cubic syngony , space group F d 3 m , cell parameters a = 0.7226 nm , Z = 8 , structure of the type of magnesium-copper Cu 2 Mg [2] [3] [4] .

The compound is formed by a peritectic reaction at a temperature of 1034 ° C [2] (1031 ° C [3] ).

Notes

  1. ↑ G. Borzone, Nadia Parodi, Riccardo Raggio, R. Ferro. Thermodynamic investigation of samarium – nickel alloys // Journal of Alloys and Compounds. - 2001 .-- T. 317-318 . - S. 532-536 . - DOI : 10.1016 / S0925-8388 (00) 01382-7 .
  2. ↑ 1 2 State Diagrams of Double Metal Systems / Ed. N.P. Lyakisheva. - M .: Engineering, 2001. - T. 3 Book 1. - 972 p. - ISBN 5-217-02843-2 .
  3. ↑ 1 2 B. Predel. Ni-Sm (Nickel-Samarium) // Landolt-Börnstein - Group IV Physical Chemistry. - 1998 .-- T. 5I . - S. 1-2 . - DOI : 10.1007 / 10542753_2264 .
  4. ↑ H. Okamoto. Ni-Sm (nickel-samarium) // Journal of Phase Equilibria. - 2001. - T. 22 , No. 1 . - S. 94 . - DOI : 10.1361 / 105497101770339427 .



Source - https://ru.wikipedia.org/w/index.php?title=Samariidinickel&oldid=88750716


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