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Pentasamaridiridium

Pentasamaridiridium is a binary inorganic compound of samarium and iridium with the formula Ir 2 Sm 5 , crystals.

Pentasamaridiridium
General
Systematic
name
Pentasamaridiridium
Traditional namesDiiridium Pentasamarium
Chem. formulaIr 2 Sm 5
Rat formulaSm 5 Ir 2
Physical properties
conditioncrystals
Molar mass1136.23 g / mol
Density9.9 g / cm³
Thermal properties
T. decomp.≈1100 ° C

Getting

  • Fusion of stoichiometric amounts of pure substances:
5Sm+2Ir→1100oCIr2Sm5{\ displaystyle {\ mathsf {5Sm + 2Ir \ {\ xrightarrow {1100 ^ {o} C}} \ Ir_ {2} Sm_ {5}}}}  

Physical Properties

Pentasamaridiridium forms monoclinic syngony crystals, space group C 2 / c , cell parameters a = 1.6144 nm , b = 0.6522 nm , c = 0.7264 nm , β = 96.7 ° , Z = 4 , dicarbide type structure pentamanganese Mn 5 C 2 [1] [2] .

The compound is formed by a peritectic reaction at a temperature of ≈1100 ° C [2] .

Notes

  1. ↑ State Diagrams of Double Metal Systems / Ed. N.P. Lyakisheva. - M .: Engineering, 2001. - T. 3 Book 1. - 972 p. - ISBN 5-217-02843-2 .
  2. ↑ 1 2 B. Predel. Ir-Sm (Iridium-Samarium) // Landolt-Börnstein - Group IV Physical Chemistry. - 1997. - T. 5G . - S. 1-2 . - DOI : 10.1007 / 10506626_1812 .



Source - https://ru.wikipedia.org/w/index.php?title= Pentasamariidiridium &oldid = 88750699


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Clever Geek | 2019