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Tritelluride disamaria

Disamarium tritelluride is a binary inorganic compound of samarium and tellurium with the formula Sm 2 Te 3 , crystals.

Tritelluride disamaria
Are common
Systematic
name
Tritelluride disamaria
Traditional namesTellurium samarium; sexvitellurid samaria
Chem. formulaSm 2 Te 3
Physical properties
conditioncrystals
Molar mass683.52 g / mol
Density7.31 g / cm³
Thermal properties
T. melt.1500 ° C
Classification
Reg. CAS number12040-00-5

Content

Getting

  • Fusion of stoichiometric amounts of pure substances:
2Sm+3Te→1500oCSm2Te3{\ displaystyle {\ mathsf {2Sm + 3Te \ {\ xrightarrow {1500 ^ {o} C}} \ Sm_ {2} Te_ {3}}}}  

Physical Properties

Disamarium tritelluride forms rhombic syngony crystals, space group P nma , cell parameters a = 1.206 nm , b = 1.186 nm , c = 0.434 nm , Z = 4 , antimony sulfide type structure Sb 2 S 3

At a temperature of 640 ° С, it passes into the cubic syngony phase, space group I 4 3d , cell parameters a = 0.9480 nm , and a structure of the tritium tetraphosphide type Th 3 P 4 [1] [2] .

The compound is formed by a peritectic reaction at a temperature of 1500 ° C [1] .

Notes

  1. ↑ 1 2 State Diagrams of Double Metal Systems / Ed. N.P. Lyakisheva. - M .: Engineering, 2000. - T. 3 Book 2. - 448 p. - ISBN 5-217-02932-3 .
  2. ↑ B. Predel. Sm-Te (Samarium-Tellurium) // Landolt-Börnstein - Group IV Physical Chemistry. - 1998 .-- T. 5J . - S. 1 . - DOI : 10.1007 / 10551312_2750 .

Literature

  • CRC Handbook of Chemistry and Physics . - 89th Edition. - Taylor and Francis Group, LLC, 2008-2009.



Source - https://ru.wikipedia.org/w/index.php?title=Tritelluride_disamaria&oldid=88750611


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