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Dirutheniumtrivungram

Diruteniumtrivungsten is a binary inorganic compound of ruthenium and tungsten with the formula W 3 Ru 2 , crystals.

Dirutheniumtrivungram
Are common
Systematic
name
Dirutheniumtrivungram
Traditional namesTrivungramdirrhenium
Chem. formulaW 3 Ru 2
Rac formulaRu 2 W 3
Physical properties
conditioncrystals
Molar mass753.66 g / mol
Density11.4 g / cm³
Thermal properties
T.2300 ° C
Classification
Reg. CAS number50645-37-9

Getting

  • Fusion of stoichiometric amounts of pure substances:
3W+2Ru→2300oCW3Ru2{\ displaystyle {\ mathsf {3W + 2Ru \ {\ xrightarrow {2300 ^ {o} C}} \ W_ {3} Ru_ {2}}}}  

Physical Properties

Dirutenium trivungsten forms tetragonal crystal crystals, the cell parameters a = 0.9349 ÷ 0.955 nm , c = 0.4855 ÷ 0.496 nm , Z = 4 [1] [2] [3] .

The compound is formed by a peritectic reaction at a temperature of 2300 ° C and at a temperature of 1667 ° C it decomposes by a eutectoid reaction [1] .

It has a wide homogeneity region of 59–67 at.% Tungsten.

Notes

  1. ↑ 1 2 State diagrams of double metallic systems / Ed. N. P. Lyakishev. - M .: Engineering, 2000. - T. 3 Book 2. - 448 p. - ISBN 5-217-02932-3 .
  2. ↑ B. Predel. Ru-W (Ruthenium-Tungsten) // Landolt-Börnstein - Group IV Physical Chemistry. - 1998 .-- T. 5J . - S. 1-2 . - DOI : 10.1007 / 10551312_2648 .
  3. ↑ Walter Obrowski. Eine σ-Phase im System Ru-W // Naturwissenschaften. - 1957. - T. 44 , No. 22 . - S. 581 . - DOI : 10.1007 / BF00630030 .


Source - https://ru.wikipedia.org/w/index.php?title=Diruteniumtrivungram&oldid=80364154


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Clever Geek | 2019