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Triruthenium uranium

Triruthenium uranium is a binary inorganic compound of uranium and ruthenium with the formula Ru 3 U, crystals.

Triruthenium uranium
Are common
Systematic
name
Triruthenium uranium
Traditional namesUrantritruthenium
Chem. formulaURu 3
Rat formulaRu 3 U
Physical properties
conditioncrystals
Molar mass541.24 g / mol
Density14.1 g / cm³
Thermal properties
T. decomp.1850 ° C
Classification
Reg. CAS number12316-42-6

Getting

  • Fusion of stoichiometric amounts of pure substances:
U+3Ru→1850oCURu3{\ displaystyle {\ mathsf {U + 3Ru \ {\ xrightarrow {1850 ^ {o} C}} \ URu_ {3}}}}  

Physical Properties

Triruthenium uranium forms crystals of cubic syngony , space group P m 3 m , cell parameters a = 0.3988 nm , Z = 1 , structure like tri - gold AuCu 3 [1] [2] [3] .

The compound is formed by a peritectic reaction at a temperature of 1850 ° C [1] or melts congruently at a temperature of 1725 ° C [3] (1725 ° C [4] ).

At a temperature of 0.15 K, the compound goes into a superconducting state [5] .

Notes

  1. ↑ 1 2 State Diagrams of Double Metal Systems / Ed. N.P. Lyakisheva. - M .: Engineering, 2000. - T. 3 Book 2. - 448 p. - ISBN 5-217-02932-3 .
  2. ↑ B. Predel. Ru-U (Ruthenium-Uranium) // Landolt-Börnstein - Group IV Physical Chemistry. - 1998 .-- T. 5J . - S. 1-2 . - DOI : 10.1007 / 10551312_2646 .
  3. ↑ 1 2 H. Okamoto. Ru-U (Ruthenium-Uranium) // Journal of Phase Equilibria and Diffusion. - 2012. - T. 33 , No. 6 . - S. 499 . - DOI : 10.1007 / s11669-012-0097-x . (inaccessible link)
  4. ↑ Richard E. Mason, Mohamed S. El-Genk. Experimental investigation of the ruthenium-uranium and rhenium-uranium binary systems // Journal of Nuclear Materials. - 1994. - T. 217 , No. 3 . - S. 304-321 . - DOI : 10.1016 / 0022-3115 (94) 90381-6 .
  5. ↑ Chen JW, Lambert SE, Maple MB, Rossel C., Torikachvili MS, Yang KN, Hake, RR Superconductivity and normal-state electronic properties of URu 3 and UCo - New behavior for U-compound superconductors // J. Appl. Phys .. - 1985. - T. 57 , No. IIA . - S. 3090-3092 . - DOI : 10.1063 / 1.335169 .


Source - https://ru.wikipedia.org/w/index.php?title=Triruteniumuran&oldid=92087670


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