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Ruthenium diphosphide

Ruthenium diphosphide is a binary inorganic compound of ruthenium and phosphorus with the formula RuP 2 , crystals.

Ruthenium diphosphide
Are common
Systematic
name
Ruthenium diphosphide
Traditional namesPhosphorous Ruthenium
Chem. formulaRuP 2
Rat formulaP 2 Ru
Physical properties
conditioncrystals
Molar mass163.02 g / mol
Density6.2 g / cmΒ³
Thermal properties
T. decomp.950 Β° C

Getting

  • Fusion of stoichiometric amounts of pure substances:
Ru+2P→650oCRuP2{\ displaystyle {\ mathsf {Ru + 2P \ {\ xrightarrow {650 ^ {o} C}} \ RuP_ {2}}}} {\displaystyle {\mathsf {Ru+2P\ {\xrightarrow {650^{o}C}}\ RuP_{2}}}}

Physical Properties

Ruthenium diphosphide forms crystals of rhombic syngony , space group Pnnm , cell parameters a = 0.5115 nm , b = 0.5888 nm , c = 0.2870 nm , Z = 2 , structure like FeS 2 iron disulfide [1] [2 ] ] .

It exhibits semiconductor properties [3] .

Chemical Properties

  • The compound decomposes at 950 Β° C [1] .
RuP2β†’950oCRuP+P↑{\ displaystyle {\ mathsf {RuP_ {2} \ {\ xrightarrow {950 ^ {o} C}} \ RuP + P \ uparrow}}} {\displaystyle {\mathsf {RuP_{2}\ {\xrightarrow {950^{o}C}}\ RuP+P\uparrow }}}

Notes

  1. ↑ 1 2 State Diagrams of Double Metal Systems / Ed. N.P. Lyakisheva. - M .: Engineering, 2001. - T. 3 Book 1. - 972 p. - ISBN 5-217-02843-2 .
  2. ↑ B. Predel. P-Ru (Phosphorus-Ruthenium) // Landolt-BΓΆrnstein - Group IV Physical Chemistry. - 1998 .-- T. 5I . - S. 1-2 . - DOI : 10.1007 / 10542753_2375 .
  3. ↑ R. Kaner, CA Castro, RP Gruska, A. Wold. Preparation and characterization of the platinum metal phosphides RuP 2 and IrP 2 // Materials Research Bulletin. - 1977. - T. 12 , No. 12 . - S. 1143-1147 . - DOI : 10.1016 / 0025-5408 (77) 90167-2 .


Source - https://ru.wikipedia.org/w/index.php?title=Ruthenium diphosphide&oldid = 94873150


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