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Ruthenium phosphide

Ruthenium phosphide is a binary inorganic compound of ruthenium and phosphorus with the formula RuP, crystals.

Ruthenium phosphide
General
Systematic
name
Ruthenium phosphide
Traditional namesPhosphorous Ruthenium
Chem. formulaRup
Rat formulaPRu
Physical properties
conditioncrystals
Molar mass132.04 g / mol
Density8.1 g / cm³
Thermal properties
T. melt.1555 ° C

Content

  • 1 Receiving
  • 2 Physical properties
  • 3 Application
  • 4 notes

Getting

  • Fusion of stoichiometric amounts of pure substances:
Ru+P→1555oCRuP{\ displaystyle {\ mathsf {Ru + P \ {\ xrightarrow {1555 ^ {o} C}} \ RuP}}}  

Physical Properties

Ruthenium phosphide forms crystals of rhombic syngony , space group P nma , cell parameters a = 0.5520 nm , b = 0.3168 nm , c = 0.6120 nm , Z = 4 , structure like manganese phosphide [1] [2] [ 3] .

The compound melts congruently at a temperature of 1555 ° C [1] .

Application

  • The catalyst in inorganic synthesis [4] .

Notes

  1. ↑ 1 2 State Diagrams of Double Metal Systems / Ed. N.P. Lyakisheva. - M .: Engineering, 2001. - T. 3 Book 1. - 972 p. - ISBN 5-217-02843-2 .
  2. ↑ B. Predel. P-Ru (Phosphorus-Ruthenium) // Landolt-Börnstein - Group IV Physical Chemistry. - 1998 .-- T. 5I . - S. 1-2 . - DOI : 10.1007 / 10542753_2375 .
  3. ↑ Rundqvist Stig. Phosphides of the B31 (MnP) Structure Type // Acta Chemica Scandinavica. - 1962.- T. 16 . - S. 287-292 . - DOI : 10.3891 / acta.chem.scand.16-0287 .
  4. ↑ Qingxin Guan, Cuiping Sun, Rongguan Li, Wei Li. The synthesis and investigation of ruthenium phosphide catalysts // Catalysis Communications. - 2011 .-- T. 14 . - S. 114–117 . - DOI : 10.1016 / j.catcom.2011.08.08.005 .


Source - https://ru.wikipedia.org/w/index.php?title=Ruthenium phosphide&oldid = 80372345


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