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Diruthenium

Dirutenium holmium is a binary inorganic compound of holmium and ruthenium with the formula HoRu 2 , crystals.

Diruthenium
Are common
Systematic
name
Diruthenium
Traditional namesHolmium
Chem. formulaHoRu 2
Rat formulaRu 2 Ho
Physical properties
conditioncrystals
Molar mass367.07 g / mol
Density11.6 g / cm³
Thermal properties
T. melt.≈1750 ° C
Enthalpy of Education-80.4 [1] kJ / mol
Classification
Reg. CAS number12055-54-8

Getting

  • Fusion of stoichiometric amounts of pure substances:
Ho+2Ru→1750oCHoRu2{\ displaystyle {\ mathsf {Ho + 2Ru \ {\ xrightarrow {1750 ^ {o} C}} \ HoRu_ {2}}}}  

Physical Properties

Dirutenium holmium forms crystals of hexagonal syngony , space group P 6 3 / mmc , cell parameters a = 0.5244 nm , c = 0.8810 nm , Z = 4 , structure like zinczinc magnesium MgZn 2 ( Laves phase ) [2] [3] [ 4] .

The compound melts congruently at a temperature of ≈1750 ° C [2] .

Notes

  1. ↑ Qiti Guo, OJ Kleppaa. Standard enthalpies of formation of some holmium alloys, Ho + Me (Me = Ni, Ru, Rh, Pd, Ir, Pt), determined by high temperature direct synthesis calorimetry // Journal of Alloys and Compounds. - 1996. - T. 234 , No. 2 . - S. 280–286 . - DOI : 10.1016 / 0925-8388 (95) 02035-7 .
  2. ↑ 1 2 State Diagrams of Double Metal Systems / Ed. N.P. Lyakisheva. - M .: Metallurgy, 1997 .-- T. 2 .-- 1024 p. - ISBN 5-217-01569-1 .
  3. ↑ B. Predel. Ho - Ru (Holmium - Ruthenium) // Landolt-Börnstein - Group IV Physical Chemistry. - 2013 .-- S. 203 . - DOI : 10.1007 / 978-3-642-24778-1_129 .
  4. ↑ B. Predel. Ho-Ru (Holmium-Ruthenium) // Landolt-Börnstein - Group IV Physical Chemistry. - 1997. - T. 5G . - S. 1-2 . - DOI : 10.1007 / 10506626_1691 .


Source - https://ru.wikipedia.org/w/index.php?title=Diruteniumholm&oldid=80364081


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