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Chloro (cyclopentadienyl) dicarbonyl ruthenium

Chloro (cyclopentadienyl) dicarbonyl ruthenium is a carbonyl complex of the organometallic ruthenium and cyclopentadiene with the formula Ru (C 5 H 5 ) (CO) 2 Cl, light yellow crystals.

Chloro
Are common
Systematic
name
Chloro (μ-cyclopentadienyl) dicarbonyl ruthenium
Chem. formulaRu (C 5 H 5 ) (CO) 2 Cl
Rat formulaRu (μ-C 5 H 5 ) (CO) 2 Cl
Physical properties
conditionlight yellow crystals
Molar mass257.64 g / mol
Thermal properties
T. melt.103 ° C

Getting

  • Ethanol and hydrochloric acid are added to a solution of bis [dicarbonyl (cyclopentadienyl) ruthenium] in chloroform , and then air is passed through the mixture:
[RuCl2(CO)3]2+HCl+O2→Ru(CfiveHfive)(CO)2Cl+H2O{\ displaystyle {\ mathsf {[RuCl_ {2} (CO) _ {3}] _ {2} + HCl + O_ {2} \ {\ xrightarrow {}} \ Ru (C_ {5} H_ {5}) (CO) _ {2} Cl + H_ {2} O}}}  

Physical Properties

Chloro (cyclopentadienyl) dicarbonyl ruthenium forms light yellow crystals.

It is steady in air.

It is well soluble in benzene , acetone , methylene chloride and chloroform . It is poorly soluble in petroleum ether .

Literature

  • Inorganic Synthesis Guide: 6 Vol. / Ed. Brower G. - M .: Mir, 1986 .-- T. 6 .-- 360 p.


Source - https://ru.wikipedia.org/w/index.php?title= Chloro ( cyclopentadienyl) dicarbonyl ruthenium &oldid = 80673448


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