Rutenocene is an organometallic sandwich compound of ruthenium with the formula Ru (C 5 H 5 ) 2 , light yellow crystals, stable in air.
| Rutenocene | |
|---|---|
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| Are common | |
| Systematic name | Rutenocene |
| Traditional names | Bis (η-cyclopentadienyl) ruthenium |
| Chem. formula | Ru (C 5 H 5 ) 2 |
| Physical properties | |
| condition | light yellow crystals |
| Molar mass | 231.26 g / mol |
| Density | 1.8 g / cm³ |
| Thermal properties | |
| T. melt. | 199-200 ° C |
| Classification | |
| Reg. CAS number | |
| PubChem | |
| Reg. EINECS number | |
| Smiles | |
| Inchi | |
| Chebi | |
| ChemSpider | |
Content
Getting
- The reaction of sodium cyclopentadienide and ruthenium trichloride in boiling tetrahydrofuran .
Physical Properties
Rutenocene forms light yellow crystals of rhombic syngony stable in air, the space group Pnma , cell parameters a = 0.713 nm, b = 0.899 nm, c = 1.281 nm, Z = 4 [1] .
It is easily cleared by sublimation in vacuum .
Notes
- ↑ GL Hardgrove, DH Templeton. The crystal structure of ruthenocene // Acta Crystallographica. - 1959. - T. 12 , No. 1 . - S. 28–32 . - DOI : 10.1107 / S0365110X59000081 .
Literature
- Inorganic Synthesis Guide: 6 Vol. / Ed. Brower G. - M .: Mir, 1986 .-- T. 6 .-- 360 p.