Dicarbonyl ruthenium dibromide

Dicarbonyl ruthenium dibromide
Dicarbonyl ruthenium dibromide
Are common
Systematic ; name	Dicarbonyl ruthenium dibromide
Traditional names	Ruthenium carbonyl bromide; dibromodicarbonyl ruthenium
Chem. formula	Ru (CO) 2 Br 2
Physical properties
condition	light orange crystals
Molar mass	316.90 g / mol
Thermal properties
T. sub.	220 ° C

Dicarbonyl ruthenium dibromide is an inorganic compound, a ruthenium carbonyl complex with the formula Ru (CO) ₂ Br ₂ , light orange crystals, does not dissolve in water.

Content

Getting

Decomposition by heating carbonyl ruthenium bromide :

{\mathsf {Ru(CO)Br\ {\xrightarrow {200^{o}C}}\ Ru(CO)_{2}Br_{2}+Ru}}

{\ displaystyle {\ mathsf {Ru (CO) Br \ {\ xrightarrow {200 ^ {o} C}} \ Ru (CO) _ {2} Br_ {2} + Ru}}}

The effect of carbon monoxide on ruthenium (III) bromide :

{\mathsf {2RuBr_{3}+4CO\ {\xrightarrow {280^{o}C}}\ 2Ru(CO)_{2}Br_{2}+Br_{2}}}

{\ displaystyle {\ mathsf {2RuBr_ {3} + 4CO \ {\ xrightarrow {280 ^ {o} C}} \ 2Ru (CO) _ {2} Br_ {2} + Br_ {2}}}}

Physical Properties

Dicarbonyl ruthenium dibromide forms light orange crystals.

Not soluble in water.

Chemical Properties

Upon reaction with nitric acid, it releases carbon monoxide and forms Ru (NO) Br ₂ .

Literature

Chemistry Handbook / Editorial: Nikolsky B.P. et al. - 3rd ed., rev. - L .: Chemistry, 1971. - T. 2. - 1168 p.
Brief chemical encyclopedia / Under. ed. Knunyants I. L. .. - M: Soviet Encyclopedia, 1965. - T. 4. - 1182 p.