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Rubidium perrenate

Rubidium perrate is an inorganic compound, the alkali metal salt of rubidium and rhenium acid with the formula RbReO 4 , colorless crystals, slightly soluble in water.

Rubidium perrenate
Are common
Systematic
name
Rubidium perrenate
Traditional namesRhenium Acid Rubidium
Chem. formulaRbreo 4
Physical properties
conditioncolorless crystals
Molar mass335.67 g / mol
Density4.73 g / cm³
Thermal properties
T. melt.598 ° C
Like heat resistant.139 J / (mol · K)
Enthalpy of Education-1089.43 [1] kJ / mol
Enthalpy of melting21 [2]
Chemical properties
Solubility in water0.389 0 ; 1.05 19 ; 1.46 25 ; 3.52 50 g / 100 ml

Content

Getting

  • Exchange reaction with perrenate sodium or rhenium acid :
NaReOfour+RbCl→RbReOfour↓+NaCl{\ displaystyle {\ mathsf {NaReO_ {4} + RbCl \ {\ xrightarrow {}} \ RbReO_ {4} \ downarrow + NaCl}}}  
HReOfour+RbCl→RbReOfour↓+HCl{\ displaystyle {\ mathsf {HReO_ {4} + RbCl \ {\ xrightarrow {}} \ RbReO_ {4} \ downarrow + HCl}}}  

Physical Properties

Rubidium perrenate forms colorless crystals of tetragonal syngony , space group I 4 1 / a , cell parameters a = 0.5903 nm , c = 1.3167 nm , Z = 4 , structure like calcium tungstate .

Slightly soluble in water.

Notes

  1. ↑ Evdokimova OV. Optimization of determination of rhenium in copper and molybdenum ore raw materials by atomic emission spectrometry with inductively coupled plasma . - Yekaterinburg: Abstract of the dissertation for the degree of candidate of chemical sciences, 2013.
  2. ↑ George J. Janz. Molten Salts Handbook . - Elsevier, 2013 .-- 602 p.

Literature

  • Chemistry Handbook / Editorial: Nikolsky B.P. et al. - 2nd ed., rev. - M.-L.: Chemistry , 1966. - T. 1. - 1072 p.
  • Plyushchev V.E., Stepin B.D. Chemistry and technology of compounds of lithium, rubidium and cesium. - M .: "Chemistry", 1970. - 408 p.



Source - https://ru.wikipedia.org/w/index.php?title=P rubrenidium perrenate&oldid = 80368682


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