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Trirtutzerium

Trruticerium is a binary inorganic compound of cerium and mercury with the formula CeHg 3 , crystals.

Trirtutzerium
Are common
Systematic
name
Trirtutzerium
Traditional namesCeriumtrrutin; amalgam of cerium
Chem. formulaCeHg 3
Rat formulaHg 3 ce
Physical properties
conditioncrystals
Molar mass741.89 g / mol
Density12.6 g / cm³
Thermal properties
T. decomp.455 ° C
Classification
Reg. CAS number12014-63-0

Getting

  • Fusion of stoichiometric amounts of pure substances in an inert atmosphere:
Ce+3Hg→455oCCeHg3{\ displaystyle {\ mathsf {Ce + 3Hg \ {\ xrightarrow {455 ^ {o} C}} \ CeHg_ {3}}}}  

Physical Properties

Tritrutzerium forms hexagonal crystals, space group P 6 3 / mmc , cell parameters a = 0.6760 nm, c = 0.4941 nm, Z = 2, cadmium magnesium type structure Mg 3 Cd [1] [2] [3] [ 4] .

The compound is formed by a peritectic reaction at a temperature of 455 ° C [1] .

Notes

  1. ↑ 1 2 State Diagrams of Double Metal Systems / Ed. N.P. Lyakisheva. - M .: Mechanical Engineering, 1996. - T. 1. - 992 p. - ISBN 5-217-02688-X .
  2. ↑ B. Predel. Ce-Hg (Cerium-Mercury) // Landolt-Börnstein - Group IV Physical Chemistry. - 1993 .-- T. 5c . - S. 1-2 . - DOI : 10.1007 / 10086082_822 .
  3. ↑ C. Guminski. The Ce-Hg (cerium-mercury) system // Journal of Phase Equilibria. - 1993. - T. 14 , No. 3 . - S. 382-387 . - DOI : 10.1007 / BF02668239 .
  4. ↑ LF Kozin, SC Hansen. Mercury Handbook: Chemistry, Applications and Environmental Impact. - Royal Society of Chemistry, 2013 .-- 322 p. - ISBN 9781849734097 .


Source - https://ru.wikipedia.org/w/index.php?title=Trirtutzerium&oldid=80371737


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