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Tetraruti triiodide diantimonide

Tetraruti triiodide-dantimonide is an inorganic compound, a mixed salt of mercury with the formula Hg 4 Sb 2 I 3 , gray-black crystals.

Tetraruti triiodide diantimonide
Are common
Systematic
name
Tetraruti triiodide diantimonide
Chem. formulaHg 4 Sb 2 I 3
Physical properties
conditiongray-black crystals
Molar mass1426.59 g / mol
Density7.79 g / cm³

Content

Getting

  • Vacuum heating of a mixture of mercury, antimony and mercury (I) iodide :
3Hg2I2+fourSb+2Hg→260-280oC2HgfourSb2I3{\ displaystyle {\ mathsf {3Hg_ {2} I_ {2} + 4Sb + 2Hg \ {\ xrightarrow {260-280 ^ {o} C}} \ 2Hg_ {4} Sb_ {2} I_ {3}}}}  
  • Vacuum heating of a mixture of mercury, antimony and mercury (II) iodide :
3HgI2+fourSb+fiveHg→260-280oC2HgfourSb2I3{\ displaystyle {\ mathsf {3HgI_ {2} + 4Sb + 5Hg \ {\ xrightarrow {260-280 ^ {o} C}} \ 2Hg_ {4} Sb_ {2} I_ {3}}}}  

Physical Properties

Tetrarcuri triiodide-dantimonide forms gray-black crystals of cubic syngony , space group Pa3, cell parameters a = 1.34392 nm, Z = 8 [1] .

Chemical Properties

  • It does not react with non-oxidizing acids, decomposes by alkalis and oxidizing acids, as well as boiling water.

Notes

  1. ↑ AV Shevelkov, EV Dikarev, BA Popovkin. The crystal structures of Hg 4 Sb 2 I 3 and Cd 4 Sb 2 I 3 // Journal of Solid State Chemistry. - 1991. - T. 93 , No. 2 . - S. 331–335 . - DOI : 10.1016 / 0022-4596 (91) 90306-3 .

Literature

  • Inorganic Synthesis Guide: 6 Vol. / Ed. Brower G. - M .: Mir, 1985 .-- T. 4 .-- 447 p.


Source - https://ru.wikipedia.org/w/index.php?title=Triiodide-diantimonide_tetrartuti&oldid=92634562


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