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Rhodiumtrivanadium

Rhodiumtrivanadium is a binary inorganic compound of rhodium and vanadium with the formula V 3 Rh, crystals.

Rhodiumtrivanadium
General
Systematic
name
Rhodiumtrivanadium
Traditional namesTrivanadium Rhodium
Chem. formulaRhV 3
Rat formulaV 3 rh
Physical properties
conditioncrystals
Molar mass255.73 g / mol
Density7.7 g / cm³
Thermal properties
T. decomp.1730 ° C
Classification
Reg. CAS number12210-74-1

Getting

  • Fusion of stoichiometric amounts of pure substances:
Rh+3V→1730oCV3Rh{\ displaystyle {\ mathsf {Rh + 3 \; V \ {\ xrightarrow {1730 ^ {o} C}} \ V_ {3} Rh}}}  

Physical Properties

Rhodiumtrivanadium forms crystals of cubic syngony , space group P m 3 n , cell parameters a = 0.4788 nm, Z = 2, trichrome silicide type structure Cr 3 Si [1] [2] [3] .

The compound is formed by a peritectic reaction at a temperature of 1730 ° C and has a large homogeneity region of 61–77 at.% Vanadium [2] .

Notes

  1. ↑ Chemist's Handbook / Editorial: Nikolsky B.P. et al. - 2nd ed., rev. - M.-L.: Chemistry, 1966. - T. 1. - 1072 p.
  2. ↑ 1 2 State Diagrams of Double Metal Systems / Ed. N.P. Lyakisheva. - M .: Engineering, 2000. - T. 3 Book 2. - 448 p. - ISBN 5-217-02932-3 .
  3. ↑ B. Predel. Rh-V (Rhodium-Vanadium) // Landolt-Börnstein - Group IV Physical Chemistry. - 1998. - T. 5 J. - S. 1-2 . - DOI : 10.1007 / 10551312_2626 .


Source - https://ru.wikipedia.org/w/index.php?title=Rhodiumtrivanadium&oldid=80934853


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