Pentarodiytricirconium is a binary inorganic compound of rhodium and zirconium with the formula Rh 5 Zr 3 , crystals.
| Pentarodiytricirconium | |
|---|---|
| Are common | |
| Systematic name | Pentarodiytricirconium |
| Traditional names | Tricyrconium pentarodium |
| Chem. formula | Rh 5 Zr 3 |
| Rac formula | Zr 3 Rh 5 |
| Physical properties | |
| condition | crystals |
| Molar mass | 788.20 g / mol |
| Density | 10.1 g / cm³ |
| Thermal properties | |
| T. | 1790 ° C |
| Education enthalpy | -626 [1] kJ / mol |
| Classification | |
| Reg. CAS number | 37382-12-0 |
Getting
- Fusion of stoichiometric amounts of pure substances:
Physical Properties
Pentarodiytricirconium forms crystals of the rhombic syngony , space group C mcm , cell parameters a = 0.85634 nm, b = 0.69860 nm, c = 0.86218 nm, Z = 4, the structure of the pentapalladium triplutonium type Pu 3 Pd 5 [2] [3 ] [4] [5] .
The compound is formed by the peritectic reaction at a temperature of 1790 ° C [2] (1780 ° C [3] ).
Notes
- ↑ Gus LW Hart, Stefano Curtarolo, Thaddeus B. Massalski, Ohad Levy. An overview of the platinum-group alloy systems // Phys. Rev. X. - 2013. - T. 3 . - p . 041035 . - DOI : 10.1103 / PhysRevX.3.041035 .
- ↑ 1 2 State diagrams of double metallic systems / Ed. N. P. Lyakishev. - M .: Mashinostroenie, 2000. - T. 3 Book 2. - 448 p. - ISBN 5-217-02932-3 .
- ↑ 1 2 B. Predel. Rh-Zr (Rhodium-Zirconium) // Landolt-Börnstein - Group IV Physical Chemistry. - 1998. - V. 5 J. - pp . 1-3 . - DOI : 10.1007 / 10551312_2631 .
- ↑ H. Okamoto. Rh-Zr (Rhodium-Zirconium) // Journal of Phase Equilibria and Diffusion. - 2004. - Vol. 25 , No. 5 . - p . 486-487 . - DOI : 10.1007 / s11669-004-0147-0 .
- ↑ D. Arias, JP Abriata. The Rh-Zr (rhodium-zirconium) system // Journal of Phase Equilibria. - 1993. - V. 14 , № 1 . - S. 110-117 . - DOI : 10.1007 / BF02652169 .