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Trirodiohepta

Trirodioheptaitrium - a binary inorganic compound of yttrium and rhodium with the formula Rh 3 Y 7 , crystals.

Trirodiohepta
General
Systematic
name
Trirodiohepta
Traditional namesHeptaitriytrirodiy
Chem. formulaRh 3 Y 7
Rat formulaY 7 Rh 3
Physical properties
conditioncrystals
Molar mass931.06 g / mol
Density6.0 g / cm³
Thermal properties
T. decomp.≈1300 ° C
Enthalpy of Education-585 [1] kJ / mol
Classification
Reg. CAS number12038-94-7

Getting

  • Sintering of stoichiometric amounts of pure substances:
7Y+3Rh→1300oCRh3Y7{\ displaystyle {\ mathsf {7 \; Y + 3 \; Rh \ {\ xrightarrow {1300 ^ {o} C}} \ Rh_ {3} Y_ {7}}}}  

Physical Properties

Trirodioheptaitrium forms crystals of hexagonal syngony , space group P 6 3 mc , cell parameters a = 0.9793 nm, c = 0.6196 nm, Z = 2, structure of the Fe 3 Th 7 heptatorium model [2] [3] .

The compound is formed by a peritectic reaction at a temperature of ≈1300 ° С [3] .

Notes

  1. ↑ Gus LW Hart, Stefano Curtarolo, Thaddeus B. Massalski, Ohad Levy. A high-throughput ab initio review of platinum-group alloy systems // Phys. Rev. X. - 2013.- T. 3 . - S. 041035 . - DOI : 10.1103 / PhysRevX . 3.041035 .
  2. ↑ State Diagrams of Double Metal Systems / Ed. N.P. Lyakisheva. - M .: Engineering, 2000. - T. 3 Book 2. - 448 p. - ISBN 5-217-02932-3 .
  3. ↑ 1 2 B. Predel. Rh-Y (Rhodium-Yttrium) // Landolt-Börnstein - Group IV Physical Chemistry. - 1998. - T. 5 J. - S. 1-2 . - DOI : 10.1007 / 10551312_2628 .


Source - https://ru.wikipedia.org/w/index.php?title=Trirodiumheptaitrium&oldid=80934916


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