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Tetra bismuth rhodium

Rhodium tetra bismuth - binary inorganic compound of rhodium and bismuth with the formula RhBi 4 , crystals.

Tetra bismuth rhodium
Are common
Systematic
name
Tetra bismuth rhodium
Traditional namesBismuth rhodium
Chem. formulaRhBi 4
Rac formulaBi 4 Rh
Physical properties
conditioncrystals
Molar mass938.83 g / mol
Thermal properties
T.460 [1] ° C
Classification
Reg. CAS number12421-85-1
SMILES

Getting

  • Fusion of stoichiometric amounts of pure substances:
Rh+fourBi→460oCRhBifour{\ displaystyle {\ mathsf {Rh + 4Bi \ {\ xrightarrow {460 ^ {o} C}} \ RhBi_ {4}}}}  

Physical Properties

Rhodium tetra bismuth forms crystals of the cubic system , space group I a 4 d , cell parameters a = 1.49274 nm, Z = 4 [1] [2] [3] .

The compound is formed by the peritectic reaction at 460 ° C [1] (466 ° C [3] ).

Notes

  1. ↑ 1 2 3 Diagrams of state of binary metallic systems / Ed. N. P. Lyakishev. - M .: Mashinostroenie, 1996. - T. 1. - 992 p. - ISBN 5-217-02688-X .
  2. ↑ B. Predel. Bi-Rh (Bismuth-Rhodium) // Landolt-Börnstein - Group IV Physical Chemistry. - 1992. - V. 5b . - p . 1-4 . - DOI : 10.1007 / 10040476_580 .
  3. ↑ 1 2 H. Okamoto. Bi-Rh (Bismuth-Rhodium) // Journal of Phase Equilibria and Diffusion. - 2010. - V. 31 , № 2 . - p . 204 . - DOI : 10.1007 / s11669-010-9660-5 .


Source - https://ru.wikipedia.org/w/index.php?title=Tetravismutid_rodiya&oldid=80370709


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