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Rhodium Triarsenide

Rhodium triarsenide is a binary inorganic compound of rhodium and arsenic with the formula RhAs 3 , crystals.

Rhodium Triarsenide
Are common
Systematic
name
Rhodium Triarsenide
Traditional namesArsenic rhodium
Chem. formulaRhAs 3
Rat formulaAs 3 rh
Physical properties
conditioncrystals
Molar mass327.67 g / mol
Density7.7 g / cm³
Classification
Reg. CAS number12256-11-0

Getting

  • Sintering of stoichiometric amounts of powdered rhodium and arsenic:
Rh+3As→TRhAs3{\ displaystyle {\ mathsf {Rh + 3As \ {\ xrightarrow {T}} \ RhAs_ {3}}}}  

Physical Properties

Rhodium triarsenide forms crystals of cubic syngony , space group I m 3 , cell parameters a = 0.8253 nm, Z = 8, cobalt triarsenide type structure CoAs 3 [1] [2] .

It is a semiconductor [3] .

Notes

  1. ↑ State Diagrams of Double Metal Systems / Ed. N.P. Lyakisheva. - M .: Mechanical Engineering, 1996. - T. 1. - 992 p. - ISBN 5-217-02688-X .
  2. ↑ B. Predel. As-Rh (Arsenic-Rhodium) // Landolt-Börnstein - Group IV Physical Chemistry. - 1991 .-- T. 5a . - S. 1 . - DOI : 10.1007 / 10000866_235 .
  3. ↑ US Patent No. 6,207,888 of April 21, 2001. Semiconductor materials with skutterudite type crystal lattice structures optimized for selected thermoelectric properties and methods of preparation . Description of the patent on the website of the United States Patent and Trademark Office .


Source - https://ru.wikipedia.org/w/index.php?title=Triarsenid_rodiya&oldid=80371309


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Clever Geek | 2019