Clever Geek Handbook
📜 ⬆️ ⬇️

Bis (chloro (pentacarbonyl) rhenium)

Bis (chloro (pentacarbonyl) rhenium) is a complex inorganic compound, a carbonyl complex of rhenium with the composition [Re (CO) 4 Cl] 2 , white crystals.

Bis
General
Systematic
name
Bis [chloro (pentacarbonyl) rhenium]
Traditional namesBis [μ-chloro (pentacarbonyl) rhenium]
Chem. formula[Re (CO) 4 Cl] 2
Physical properties
conditionwhite crystals
Molar mass667.40 g / mol

Getting

  • The addition of carbon tetrachloride saturated with chlorine to a suspension of decacarbonyldirehenia in carbon tetrachloride :
Re2(CO)10+Cl2→[Re(CO)fourCl]2+2CO{\ displaystyle {\ mathsf {Re_ {2} (CO) _ {10} + Cl_ {2} \ {\ xrightarrow {}} \ [Re (CO) _ {4} Cl] _ {2} + 2CO}} }  

Physical Properties

Bis (chloro (pentacarbonyl) rhenium) forms white crystals that are stable in air. Not soluble in aliphatic hydrocarbons , poorly soluble in carbon tetrachloride .

Literature

  • Inorganic Synthesis Guide: 6 Vol. / Ed. Brower G. - M .: Mir, 1986 .-- T. 6 .-- 360 p.



Source - https://ru.wikipedia.org/w/index.php?title=Bis ( chloro ( pentacarbonyl) rhenium )&oldid = 80663472


More articles:

  • Muli (river)
  • Denigomodu
  • Andrey Alexandrovich
  • Vladimirsky, Mikhail Fedorovich
  • Victory Records
  • Mongolia Men's International Drafts Championship 2015
  • Violeta went to heaven
  • Velgartice Castle
  • Boyan
  • Ural County

All articles

Clever Geek | 2019