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Octafluoride Oxide Diprotactinium

Octafluoride oxide diprotactinium is an inorganic compound of protactinium , oxygen and fluorine with the formula Pa 2 OF 8 , colorless crystals.

Octafluoride Oxide Diprotactinium
Are common
Systematic
name
Octafluoride Oxide Diprotactinium
Traditional namesProtaktinium fluoride
Chem. formulaPa 2 OF 8
Rac formulaPa 2 F 8 O
Physical properties
conditioncolorless crystals
Molar mass630.06 g / mol
Density7.0 g / cm³
Classification
Reg. CAS number12400-84-9

Content

Getting

  • Heating crystalline hydrate of protaktinium fluoride (V) in air [1] [2] :
2PaFfive⋅2H2O→160oCPa2OFeight+2HF+3H2O{\ displaystyle {\ mathsf {2PaF_ {5} \ cdot 2H_ {2} O \ {\ xrightarrow {160 ^ {o} C}} \ Pa_ {2} OF_ {8} + 2HF + 3H_ {2} O}} }  
  • Passing a mixture of hydrogen fluoride and oxygen through protaktinium oxide (V) [1] [2] :
Pa2Ofive+eightHF→140-160oC,O2Pa2OFeight+fourH2O{\ displaystyle {\ mathsf {Pa_ {2} O_ {5} + 8HF \ {\ xrightarrow {140-160 ^ {o} C, O_ {2}} \ Pa_ {2} OF_ {8} + 4H_ {2 } O}}}  

Physical Properties

Octafluoride-oxide diprotactin forms colorless crystals of the cubic system , the cell parameters are a = 0.84065 nm, Z = 4 is a structure of the non-fluoride type of diuran U 2 F 9 [1] .

The molecule has the structure of F 4 Pa-O-PaF 4 [2] .

Chemical Properties

  • Decomposed by heating to protaktinium fluoride dioxide [3] [4] :
2Pa2OFeight→250-290oC3PaFfive+PaO2F{\ displaystyle {\ mathsf {2Pa_ {2} OF_ {8} \ {\ xrightarrow {250-290 ^ {o} C}} \ 3PaF_ {5} + PaO_ {2} F}}}  

Notes

  1. 2 1 2 3 The Chemistry of the Actinide and Transactinide Elements / Lester R. Morss, Norman M. Edelstein, J. Fuger. - Springer, 2010. - Vol. 1. - 874 p. - ISBN 978-94-007-0210-3 .
  2. ↑ 1 2 3 Palshin E.S., Myasoedov B.F., Davydov A.V. Analytical chemistry of protactinium. - M: Science, 1968. - 241 p.
  3. ↑ G. Meyer, Lester R. Morss. Synthesis of Lanthanide and Actinide Compounds . - Springer Science & Business Media, 2012. - 368 p. - ISBN 978-94-011-3758-4 . - DOI : 10.1007 / 978-94-011-3758-4 .
  4. ↑ D. Brown, JF Easey. Protactinium (V) fluorides // Journal of the Chemical Society A: Inorganic, Physical, Theoretical. - 1970. - p . 3378-3381 . - DOI : 10.1039 / j19700003378 .


Source - https://ru.wikipedia.org/w/index.php?title=Octafluoride-oxide_diproactinium&oldid=87620809


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