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Tripraseodymium nickel

Tripraseodymium nickel is a binary inorganic compound of praseodymium and nickel with the formula NiPr 3 , crystals.

Tripraseodymium nickel
General
Systematic
name
Tripraseodymium nickel
Traditional namesNickeltripraseodymium
Chem. formulaPr 3 Ni
Rat formulaNipr 3
Physical properties
conditioncrystals
Molar mass481.42 g / mol
Density6.9 g / cm³
Thermal properties
T. melt.525 ° C [1] ; 530 ° C [2] ; 562 ° C [3]
Classification
Reg. CAS number12363-00-7

Getting

  • Fusion of stoichiometric amounts of pure substances:
3Pr+Ni→530oCNiPr3{\ displaystyle {\ mathsf {3Pr + Ni \ {\ xrightarrow {530 ^ {o} C}} \ NiPr_ {3}}}}  

Physical Properties

Tripraseodymium nickel forms crystals of rhombic syngony , space group P nma , cell parameters a = 0.707 nm, b = 0.996 nm, c = 0.649 nm, Z = 4, structure like iron carbide Fe 3 C [2] [1] [4] [5 ] ] .

The compound melts congruently at a temperature of 530 ° C [2] (525 ° C [1] , 562 ° C [3] ).

Notes

  1. ↑ 1 2 3 H. Okamoto. Ni-Pr (nickel-praseodymium) // Journal of Phase Equilibria and Diffusion. - 2005. - T. 26 , No. 6 . - S. 650 . - DOI : 10.1007 / s11669-005-0023-6 .
  2. ↑ 1 2 3 State Diagrams of Double Metal Systems / Ed. N.P. Lyakisheva. - M .: Engineering, 2001. - T. 3 Book 1. - 972 p. - ISBN 5-217-02843-2 .
  3. ↑ 1 2 M. Huang, D. Wu, KW Dennis, JW Anderegg, RW McCallum, TA Lograsso. The Pr-rich portion of the Ni-Pr system // Journal of Phase Equilibria and Diffusion. - 2005. - T. 26 , No. 3 . - S. 209-214 . - DOI : 10.1007 / s11669-005-0107-3 .
  4. ↑ H. Okamoto. Ni-Pr (Nickel-Praseodymium) // Journal of Phase Equilibria. - 2001. - T. 22 , No. 4 . - S. 513 . - DOI : 10.1361 / 105497101770338617 .
  5. ↑ B. Predel. Ni-Pr (Nickel-Praseodymium) // Landolt-Börnstein - Group IV Physical Chemistry. - 1998 .-- T. 5I . - S. 1-2 . - DOI : 10.1007 / 10542753_2253 .


Source - https://ru.wikipedia.org/w/index.php?title= Tripraseodymium nickel&oldid = 80371657


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