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Praseodymium tetramed

Praseodymium tetramedium is a binary inorganic compound of praseodymium and copper with the formula Cu 4 Pr, crystals.

Praseodymium tetramed
Are common
Systematic
name
Praseodymium tetramed
Traditional namesTetramecodraseodymium
Chem. formulaPrCu 4
Rat formulaCu 4 Pr
Physical properties
conditioncrystals
Molar mass395.09 g / mol
Density7.7 g / cm³
Thermal properties
T. decomp.824 ° C [1]
Enthalpy of Education-27.8 [2] kJ / mol

Getting

  • Fusion of stoichiometric amounts of pure substances:
Pr+fourCu→824oCPrCufour{\ displaystyle {\ mathsf {Pr + 4Cu \ {\ xrightarrow {824 ^ {o} C}} \ PrCu_ {4}}}}  

Physical Properties

Praseodymium tetra gum forms rhombic syngony crystals, space group Pnnm , cell parameters a = 0.454 nm, b = 0.808 nm, c = 0.922 nm, Z = 4, tetromedium cerium type structure CeCu 4 [1] [3] [2] .

The compound is formed by a peritectic reaction at a temperature of 824 ° C [1] .

Notes

  1. ↑ 1 2 3 State Diagrams of Double Metal Systems / Ed. N.P. Lyakisheva. - M .: Metallurgy, 1997 .-- T. 2 .-- 1024 p. - ISBN 5-217-01569-1 .
  2. ↑ 1 2 PR Subramanian and DE Laughlin. The Cu-Pr (Copper-Praseodymium) System // Bulletin of Alloy Phase Diagrams. - 1988. - T. 9 , No. 3a . - S. 372-377 .
  3. ↑ B. Predel. Cu-Pr (Copper-Praseodymium) // Landolt-Börnstein - Group IV Physical Chemistry. - 1994 .-- T. 5d . - S. 1-3 . - DOI : 10.1007 / 10086090_1105 .


Source - https://ru.wikipedia.org/w/index.php?title=Praseodymium tetramed&oldid = 80369184


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