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Praseodymiumcadmium

Praseodymiumcadmium is a binary inorganic compound, an intermetallic compound of praseodymium and cadmium with the formula CdPr, crystals.

Praseodymiumcadmium
Are common
Systematic
name
Praseodymiumcadmium
Traditional namesCadmium praseodymium
Chem. formulaPrcd
Rat formulaCdpr
Physical properties
conditioncrystals
Molar mass253.32 g / mol
Density7.5 g / cm³
Thermal properties
T. melt.> 700 ° C [1] ; 1003 ° C [2]

Getting

  • Fusion of stoichiometric amounts of pure substances:
Pr+Cd→TCdPr{\ displaystyle {\ mathsf {Pr + Cd \ {\ xrightarrow {T}} \ CdPr}}} {\displaystyle {\mathsf {Pr+Cd\ {\xrightarrow {T}}\ CdPr}}}

Physical Properties

Praseodymium cadmium forms crystals of cubic syngony , space group P m 3 m , cell parameters a = 0.3830 nm, Z = 1, structure of the type of cesium chloride CsCl [3] [4] [1] .

The compound melts congruently at a temperature of 1003 ° C [2] and forms a eutectic with praseodymium with a melting point of 435 ° C [5] .

Notes

  1. ↑ 1 2 KA Gschneidner, FW Calderwood. The Cd − Pr (Cadmium-Praseodymium) system // Journal of Phase Equilibria. - 1988. - T. 9 , No. 2 . - S. 130-132 . - DOI : 10.1007 / BF02890545 .
  2. ↑ 1 2 Thomas L. Reichmann, Klaus W. Richter, Simona Delsante, Gabriella Borzone, Herbert Ipser. Enthalpies of formation of Cd – Pr intermetallic compounds and thermodynamic assessment of the Cd – Pr system // CALPHAD: Computer Coupling of Phase Diagrams and Thermochemistry. - 2014 .-- T. 47 . - S. 56–62 . - DOI : 10.1016 / j.calphad.2014.06.06.005 .
  3. ↑ State Diagrams of Double Metal Systems / Ed. N.P. Lyakisheva. - M .: Mechanical Engineering, 1996. - T. 1. - 992 p. - ISBN 5-217-02688-X .
  4. ↑ B. Predel. Cd-Pr (Cadmium-Praseodymium) // Landolt-Börnstein - Group IV Physical Chemistry. - 1993 .-- T. 5c . - S. 1-2 . - DOI : 10.1007 / 10086082_782 .
  5. ↑ KA Gschneidner, FW Calderwood. The cadmium-rare earth systems // Bulletin of Alloy Phase Diagrams. - 1988. - T. 9 , No. 1 . - S. 16-21 . - DOI : 10.1007 / BF02877448 .


Source - https://ru.wikipedia.org/w/index.php?title=Praseodymiumcadmium&oldid=81020659


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