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Tetrapraseodymium triarsenide

Tetrapraseodymium triarsenide is a binary inorganic compound of praseodymium and arsenic with the formula Pr 4 As 3 , crystals.

Tetrapraseodymium triarsenide
Are common
Systematic
name
Tetrapraseodymium triarsenide
Traditional namesArsenic praseodymium
Chem. formulaPr 4 As 3
Physical properties
conditioncrystals
Molar mass788.40 g / mol
Density7.2 g / cm³

Getting

  • Fusion of stoichiometric amounts of pure substances:
fourPr+3As→TPrfourAs3{\ displaystyle {\ mathsf {4Pr + 3As \ {\ xrightarrow {T}} \ Pr_ {4} As_ {3}}}} {\displaystyle {\mathsf {4Pr+3As\ {\xrightarrow {T}}\ Pr_{4}As_{3}}}}

Physical Properties

Tetrapraseodymium triarsenide forms cubic syngony crystals, space group I 4 3d , cell parameters a = 0.8984 nm, Z = 4, structure of the tritium tetraphosphide type Th 4 P 3 [1] [2] [3] [4] .

Notes

  1. ↑ State Diagrams of Double Metal Systems / Ed. N.P. Lyakisheva. - M .: Mechanical Engineering, 1996. - T. 1. - 992 p. - ISBN 5-217-02688-X .
  2. ↑ KA Gschneidner, FW Calderwood. The As − Pr (Arsenic-Praseodymium) system // Bulletin of Alloy Phase Diagrams. - 1986. - T. 7 , No. 4 . - S. 347-348 . - DOI : 10.1007 / BF02873010 .
  3. ↑ Wolfhart Rieger, Erwin Parthé. Die Kristallstruktur von Ce 4 As 3 und Pr 4 As 3 // Monatshefte für Chemie / Chemical Monthly. - 1969. - T. 100 , No. 4 . - S. 1370-1371 . - DOI : 10.1007 / BF00903473 .
  4. ↑ KA Gschneidner, FW Calderwood. The arsenic-rare earth systems // Bulletin of Alloy Phase Diagrams. - 1986. - T. 7 , No. 3 . - S. 274-276 . - DOI : 10.1007 / BF02869005 .



Source - https://ru.wikipedia.org/w/index.php?title=Trirapenis_tetrapraseodymium&oldid=80371313


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