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Praseodymium (III) bromide oxide

Praseodymium (III) bromide oxide is an inorganic compound, praseodymium and hydrobromic acid oxosol with the formula PrOBr, crystals.

Praseodymium bromide oxide
General
Systematic
name
Praseodymium (III) bromide oxide
Traditional namesPraseodymium bromide
Chem. formulaPrOBr
Physical properties
conditioncrystals
Molar mass236.81 g / mol
Density6.3 g / cm³
Thermal properties
T. decomp.430-700 ° C

Content

  • 1 Receiving
  • 2 Physical properties
  • 3 Chemical properties
  • 4 notes
  • 5 Literature

Getting

  • The decomposition of crystalline hydrate of praseodymium bromide (III) when heated:
PrBr3⋅xH2O→one hundred-350oCPrOBr+2HBr+(x-one)H2O{\ displaystyle {\ mathsf {PrBr_ {3} \ cdot {\ mathit {x}} H_ {2} O \ {\ xrightarrow {100-350 ^ {o} C}} \ PrOBr + 2HBr + {\ mathit {(x -1)}} H_ {2} O}}}  

Physical Properties

Praseodymium (III) bromide forms tetragonal crystal crystals, space group P 4 / nmm , cell parameters a = 0.40671 nm, c = 0.74669 nm, Z = 2, PbFCl type structure [1] .

Chemical Properties

  • It decomposes on heating in air at a temperature of 430-700 ° C.

Notes

  1. ↑ P. Talmon-Gros, CM Schurz, T. Schleid. The matlockite-type praseodymium (III) oxide bromide PrOBr // Acta Cryst .. - 2011.- T. E67 , No. 12 . - S. i74 . - DOI : 10.1107 / S1600536811048227 .

Literature

  • Inorganic Synthesis Guide: 6 Vol. / Ed. Brower G. - M .: Mir, 1985 .-- T. 4 .-- 447 p.


Source - https://ru.wikipedia.org/w/index.php?title= Oxide- praseodymium bromide ( III)&oldid = 80367454


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