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Praseodymium (III) fluoride

Praseodymium (III) fluoride is a binary inorganic compound, a salt of praseodymium metal and hydrofluoric acid with the formula PrF 3 , pale green crystals, does not dissolve in water.

Praseodymium fluoride
Are common
Systematic
name
Praseodymium (III) fluoride
Traditional namesPraseodymium fluoride
Chem. formulaPrF 3
Physical properties
conditionpale green crystals
Molar mass197.90 g / mol
Density6.2; 6.3 g / cm³
Thermal properties
T. melt.1373; 1395; 1399; 1400 ° C
T. Kip.2300; 2330 ° C
Mol heat capacity103.34 J / (mol · K)
Education enthalpy-1689 kJ / mol
Classification
Reg. CAS number13709-46-1
Pubchem
Reg. EINECS number237-254-9
SMILES
Inchi
Chemspider

Content

Getting

  • Effect of hydrogen fluoride gas on hexapraseodymium undecaoxide
Pr6Oeleven+18HF→600oC6PrF3+9H2O+O2{\ displaystyle {\ mathsf {Pr_ {6} O_ {11} + 18HF \ {\ xrightarrow {600 ^ {o} C}} \ 6PrF_ {3} + 9H_ {2} O + O_ {2}}}}  

Physical Properties

Praseodymium (III) fluoride forms pale green crystals of trigonal syngony [1] (or hexagonal syngony [2] ), space group P 3 c1 [1] (or P 6 / mcm [2] ), cell parameters a = 0.7078 nm, c = 0.7239 nm, Z = 6, the structure of the cerium fluoride type CeF 3 .

Not soluble in water.

Application

  • Getting praseodymium metallothermic method.
  • Component of fluoride laser materials.

Notes

  1. ↑ 1 2 Chemical encyclopedia / Redcol .: Knunyants I.L. et al. - M .: Soviet Encyclopedia, 1995. - Vol. 4. - 639 p. - ISBN 5-82270-092-4 .
  2. ↑ 1 2 Chemist Handbook / Redkol .: B. Nikolsky et al. - 2nd ed., Rev. - M.-L.: Chemistry, 1966. - T. 1. - 1072 p.

Literature

  • Chemist Handbook / Redkol .: Nikolsky B.P. et al. - 3rd ed., Rev. - L .: Chemistry, 1971. - T. 2. - 1168 p.
  • Chemical Encyclopedic Dictionary / Redkol .: Knunyants I.L. et al. - M .: Soviet Encyclopedia, 1983. - 792 p.
  • CRC Handbook of Chemistry and Physics . - 89th edition. - Taylor and Francis Group, LLC, 2008-2009.


Source - https://ru.wikipedia.org/w/index.php?title=Fluoride_praeodymium ( IIIIII&&oldid = 80372517


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