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Palladium barium

Palladium barium is a binary inorganic compound of palladium and barium with the formula BaPd 5 , crystals.

Palladium barium
Are common
Systematic
name
Palladium barium
Traditional namesBarium palladium
Chem. formulaPdba
Rat formulaBapd
Physical properties
conditioncrystals
Molar mass243.75 g / mol
Density6.7 g / cm³
Thermal properties
T. decomp.> 1100 ° C
Classification
Reg. CAS number55127-37-2

Getting

  • Fusion of stoichiometric amounts of pure substances:
Pd+Ba→>1100oCBaPd{\ displaystyle {\ mathsf {Pd + Ba \ {\ xrightarrow {> 1100 ^ {o} C}} \ BaPd}}}  

Physical Properties

Palladium barium forms crystals of rhombic syngony , space group C mcm , cell parameters a = 0.435 nm, b = 1.179 nm, c = 0.468 nm, Z = 4, structure like chromium boride CrB [1] [2] [3] .

There are data on other parameters of monoclinic syngony , cell parameters a = 0.4352 nm, b = 0.4683 nm, c = 0.6283 nm, β = 110.25 °, Z = 2 [4] .

Notes

  1. ↑ State Diagrams of Double Metal Systems / Ed. N.P. Lyakisheva. - M .: Mechanical Engineering, 1996. - T. 1. - 992 p. - ISBN 5-217-02688-X .
  2. ↑ H. Okamoto. The Ba-Pd (Barium-Palladinum) system // Journal of Phase Equilibria. - 1991. - T. 12 , No. 4 . - S. 462-464 . - DOI : 10.1007 / BF02645969 .
  3. ↑ G. Bruzzone, F. Merlo. Crystal chemical remarks on the alloying behavior of calcium, strontium and barium // Journal of the Less Common Metals. - 1982.- T. 85 . - S. 285-306 . - DOI : 10.1016 / 0022-5088 (82) 90077-7 .
  4. ↑ Richard C. Ropp ,. Encyclopedia of the Alkaline Earth Compounds. - Elsevier, 2013 .-- 1187 p. - ISBN 978-0-444-59550-8 .
Source - https://ru.wikipedia.org/w/index.php?title=Palladium barium&oldid = 80368064


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