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Tetraplatin pentaitrium

Tetraplatinapentaitrium - a binary inorganic compound of platinum and yttrium with the formula Pt 4 Y 5 , crystals.

Tetraplatin pentaitrium
Are common
Systematic
name
Tetraplatin pentaitrium
Traditional namesTriittrium tetraplatin
Chem. formulaPt 4 Y 5
Rat formulaY 5 Pt 4
Physical properties
conditioncrystals
Molar mass1224.84 g / mol
Density9.97 g / cm³
Thermal properties
T. decomp.≈1700 [1] ° C
Enthalpy of Education-120 [2] kJ / mol

Getting

  • Fusion of stoichiometric amounts of pure substances:
fourPt+fiveY→1700oCPtfourYfive{\ displaystyle {\ mathsf {4Pt + 5Y \ {\ xrightarrow {1700 ^ {o} C}} \ Pt_ {4} Y_ {5}}}}  

Physical Properties

Tetraplatinapentaitrite forms rhombic syngony crystals, space group P nma , cell parameters a = 0.7458 nm, b = 1.4546 nm, c = 0.7519 nm, Z = 4, pentasamarium tetra germanium type structure Ge 4 Sm 5 [1] [3 ] ] [4] .

The compound is formed by a peritectic reaction at a temperature of ≈1700 ° C [1] .

Notes

  1. ↑ 1 2 3 State Diagrams of Double Metal Systems / Ed. N.P. Lyakisheva. - M .: Engineering, 2000. - T. 3 Book 2. - 448 p. - ISBN 5-217-02932-3 .
  2. ↑ Thermodynamic modeling of the platinum yttrium system.
  3. ↑ A. Palenzona, S. Cirafici. The Pt-Y (Platinum-Yttrium) system // Bulletin of Alloy Phase Diagrams. - 1990. - T. 11 , No. 5 . - S. 493-497 . - DOI : 10.1007 / BF02898267 .
  4. ↑ J. Le Roy, J.-M. Moreau, D. Paccard, E. Parthé. R 5 Pt 4 compounds (R = Tb, Dy, Ho, Er, Tm, Lu and Y) isotypic with Pu 5 Rh 4 // Acta Crystallographica Section B. - 1978. - T. 34 , No. 11 . - S. 3315–3318 . - DOI : 10.1107 / S0567740878010742 .


Source - https://ru.wikipedia.org/w/index.php?title=Tetraplatinapentaitrium&oldid=93493113


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Clever Geek | 2019